journal article·2024-09-10

Self-Assemblies of Carboxylic Acid Derivatives with Different Symmetry: Adjusting by Solvent and Guest Molecules

Shuai Wang, Peng Lei, Zhizhong Huang, Luan He, Siqi Zhang, Qingyu Liu, Ke Deng, Qingdao Zeng

Langmuir· Volume 40· Issue 36
Publisher page

Abstract

In this research, the self-assembly behaviors of two different symmetry carboxylic acid derivatives ( H 3 BTE and H 4 BTE ) regulated by solvent and guest molecule (coronene, COR) were explored at the liquid/solid interface by scanning tunneling microscopy, and the formation mechanism was investigated by density functional theory. In 1-phenyloctane, only H 3 BTE molecules dissolved with extremely low concentration and self-assembled into a honeycomb structure and a new strip structure, while H 4 BTE could not. In 1-heptanoic acid, H 3 BTE and H 4 BTE were easily dissolved, in which H 3 BTE formed a regular row structure and H 4 BTE formed a tetragonal structure, respectively. The host–guest interaction was investigated by introducing the COR molecules into their self-assembly structures, and due to the different symmetry, H 3 BTE and H 4 BTE displayed different accommodation behavior.
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Research context

OpenAlex topics: Surface Chemistry and Catalysis · Supramolecular Self-Assembly in Materials · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Engineering, Shenyang Agricultural University, Shenyang 110866, China

CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology (NCNST), Beijing 100190, China

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Jiangxi College of Applied Technology, Ganzhou 341000, China

Guangdong Engineering and Technology Research Center for Advanced Nanomaterials, School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, China

Funding

Department of Education of Liaoning Province · National Natural Science Foundation of China · Chinese Academy of Sciences · GuangDong?Basic?and?Applied?Basic?Research?Foundation · Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. · Engineering Research Center of Nano Geomaterials of Ministry of Education

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