journal article·2023-09-26

P-Band Intermediate States Mediate Electron Transfer at Confined Nanoscale

Bo Peng, Kun Zhang, Ming-Yuan He

Langmuir· Volume 39· Issue 38
Publisher page

Abstract

In this Perspective, mainly based on the model of structural water molecules (SWs) as bright color emitters, we briefly summarize the development and theoretical elaboration of P-band intermediate state (PBIS) theory as well as its application in several typical catalytic redox reactions. In addition, with a simple equation (2∫ψ 2 σ1′ + ∫ψ 2 σ2 + ∫ψ 2 π = 1), we clearly define how the interface states correlate with the three basic parameters of heterogeneous catalysis (conversion, selectivity, and stability), and what is the dynamic nature of catalytic active sites. Overall, the proposal of SW-dominated PBIS theory establishes an internal physical connection between the decay kinetics of excited electrons and the catalytic reaction kinetics and provides new insights into the physical origin of photoluminescence emission of low-dimensional quantum nanodots and the physical nature of nanoconfinement and nanoconfined catalysis.
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Research context

OpenAlex topics: Nanocluster Synthesis and Applications · Quantum Dots Synthesis And Properties · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, College of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, Sinopec Research Institute of Petroleum Processing Co., Ltd., Beijing 100083, China

State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, East China Normal University, Shanghai 200062, China

Laboratoire de Chimie, Ecole Normale Supérieure de Lyon, Institut de Chimie de Lyon, Université de Lyon, 46 Allée d’italie, Lyon 69364, CEDEX 07, France

Institute of Eco-Chongming, Shanghai 202162, China

Funding

East China Normal University · National Key Research and Development Program of China · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · Joint Research Institute for Science and Society · Joint laboratory for Low Carbon Energy and Chemical Processes · Shanghai Curui Low-Carbon Energy Technology Co., Ltd.

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