Solvent-Free One-Pot Synthesis of Epoxy Nanocomposites Containing Mg(OH)₂Nanocrystal–Nanoparticle Formation Mechanism

Francesco Branda; Jessica Passaro; Robin Pauer; Sabyasachi Gaan; Aurelio Bifulco

doi:10.1021/acs.langmuir.2c00377

journal article·2022-05-10Open access

Solvent-Free One-Pot Synthesis of Epoxy Nanocomposites Containing Mg(OH)₂Nanocrystal–Nanoparticle Formation Mechanism

Francesco Branda, Jessica Passaro, Robin Pauer, Sabyasachi Gaan, Aurelio Bifulco

Langmuir· Volume 38· Issue 18

Publisher page Open full text

Source abstract

Abstract

(001) planes. The synthesis of MgNCs was designed on the basis of a mechanism initially proposed for the preparation of multisheet-silica-based/epoxy nanocomposites. The successful "in situ" generation of MgNCs in the epoxy via a "solvent-free one-pot" process confirms the validity of the earlier disclosed mechanism and thus opens up possibilities of new NCs with different fillers and polymer matrix. The condition would be the availability of a nanoparticle precursor soluble in the hydrophobic resin, giving the desired phase through hydrolysis and polycondensation.

Source: openalex_inverted_index · Quality: baseline

Research context

Polymers Nanomaterials

OpenAlex topics: Magnesium Oxide Properties and Applications · Polymer Nanocomposites and Properties · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Materials and Industrial Production Engineering (DICMaPI), University of Naples Federico II, 80125 Naples, Italy

Advanced Materials and Surfaces Fibers, Empa Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dubendorf, Switzerland

Laboratory for Advanced Fibers, Empa Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, 9014 St. Gallen, Switzerland

References (89)

Show source-provided references

1. 10.1016/j.desal.2005.06.04210.1016/j.desal.2005.06.042 ↗

2. 10.1021/ie504265z10.1021/ie504265z ↗

3. 10.1021/ie801159810.1021/ie8011598 ↗

4. 10.1016/S0142-9612(01)00101-610.1016/S0142-9612(01)00101-6 ↗

5. He Z. · J. Pulp Pap. Sci. · 2006 · 32 · 47

6. 10.1016/j.ceramint.2014.04.07310.1016/j.ceramint.2014.04.073 ↗

7. 10.1016/j.jallcom.2011.09.08910.1016/j.jallcom.2011.09.089 ↗

8. 10.1007/s11051-009-9769-910.1007/s11051-009-9769-9 ↗

9. 10.1016/j.materresbull.2010.12.02310.1016/j.materresbull.2010.12.023 ↗

10. 10.1016/j.memsci.2011.10.00710.1016/j.memsci.2011.10.007 ↗

11. 10.1016/j.matlet.2014.07.11010.1016/j.matlet.2014.07.110 ↗

12. 10.1088/0957-4484/15/11/03510.1088/0957-4484/15/11/035 ↗

13. 10.1039/C8DT02949K10.1039/C8DT02949K ↗

14. 10.1016/j.proeng.2013.02.15010.1016/j.proeng.2013.02.150 ↗

15. 10.1002/(SICI)1097-4628(19960531)60:9<1425::AID-APP18>3.0.CO;2-010.1002/(SICI)1097-4628(19960531)60:9<1425::AID-APP18>3.0.CO;2-0 ↗

16. 10.1016/j.polymdegradstab.2007.06.00410.1016/j.polymdegradstab.2007.06.004 ↗

17. 10.1016/S0141-3910(96)00067-510.1016/S0141-3910(96)00067-5 ↗

18. 10.1007/s10853-011-5933-610.1007/s10853-011-5933-6 ↗

19. 10.1021/jp035340w10.1021/jp035340w ↗

20. 10.1021/cm000676t10.1021/cm000676t ↗

21. 10.1016/j.ceramint.2007.03.03410.1016/j.ceramint.2007.03.034 ↗

22. 10.1007/s13391-012-2062-610.1007/s13391-012-2062-6 ↗

23. Jadhav S. D. · Pharma Innovation · 2018 · 7 · 380

24. Rothon, R. N.Magnesium Hydroxide: New Products, Processes and Appications, 2000.

25. Martins, M.; Pereira, C.A Study on the Effect of Nano-magnesium Hydroxide on the Flammability of Epoxy Resins; Trans Tech Publications, 2009; pp 72–78.10.4028/www.scientific.net/SSP.151.72 ↗

26. 10.1016/j.compositesa.2003.09.02110.1016/j.compositesa.2003.09.021 ↗

27. 10.1163/092764410X51334110.1163/092764410X513341 ↗

28. Guglielmi M. · 201410.1007/978-1-4939-1209-4 ↗

29. 10.3390/surfaces304004410.3390/surfaces3040044 ↗

30. 10.1021/acsmacrolett.8b0095610.1021/acsmacrolett.8b00956 ↗

31. 10.1016/j.pmatsci.2020.10066310.1016/j.pmatsci.2020.100663 ↗

32. 10.1007/s10971-011-2465-010.1007/s10971-011-2465-0 ↗

33. 10.1039/C6TC01210H10.1039/C6TC01210H ↗

34. 10.1039/C5TA07115A10.1039/C5TA07115A ↗

35. 10.1002/adfm.20150378210.1002/adfm.201503782 ↗

36. 10.3390/polym808028110.3390/polym8080281 ↗

37. 10.1021/la503361k10.1021/la503361k ↗

38. 10.1021/acs.langmuir.5b0445710.1021/acs.langmuir.5b04457 ↗

39. 10.1021/la035691210.1021/la0356912 ↗

40. 10.1021/acs.langmuir.9b0276110.1021/acs.langmuir.9b02761 ↗

41. 10.1246/bcsj.2017000510.1246/bcsj.20170005 ↗

42. 10.1016/S0032-3861(98)00214-610.1016/S0032-3861(98)00214-6 ↗

43. 10.1002/pen.2037210.1002/pen.20372 ↗

44. 10.1007/s10853-005-3653-510.1007/s10853-005-3653-5 ↗

45. 10.1002/adv.2003310.1002/adv.20033 ↗

46. 10.1007/s10971-005-2290-410.1007/s10971-005-2290-4 ↗

47. 10.1016/j.polymer.2010.09.05910.1016/j.polymer.2010.09.059 ↗

48. 10.1016/j.polymer.2011.01.04610.1016/j.polymer.2011.01.046 ↗

49. 10.1007/s10973-012-2267-910.1007/s10973-012-2267-9 ↗

50. 10.1007/s10965-013-0202-910.1007/s10965-013-0202-9 ↗

51. 10.1002/mame.20120022210.1002/mame.201200222 ↗

52. 10.1016/j.polymer.2015.03.01210.1016/j.polymer.2015.03.012 ↗

53. 10.1016/j.porgcoat.2014.05.01810.1016/j.porgcoat.2014.05.018 ↗

54. 10.1002/vnl.2141410.1002/vnl.21414 ↗

55. 10.1016/j.porgcoat.2014.04.00510.1016/j.porgcoat.2014.04.005 ↗

56. Brinker C. J. · 2013

57. 10.1016/0021-9797(68)90272-510.1016/0021-9797(68)90272-5 ↗

58. Branda F. · Advances in Nanocomposites - Synthesis, Characterization and Industrial Applications · 2011 · 14 · 323

59. 10.1021/acsapm.1c0124010.1021/acsapm.1c01240 ↗

60. 10.1007/s10971-018-4710-210.1007/s10971-018-4710-2 ↗

61. 10.1021/acs.langmuir.1c0136310.1021/acs.langmuir.1c01363 ↗

62. 10.3390/polym1208166110.3390/polym12081661 ↗

63. 10.1016/j.jcomc.2020.10002210.1016/j.jcomc.2020.100022 ↗

64. 10.1016/j.matdes.2020.10886210.1016/j.matdes.2020.108862 ↗

65. 10.1557/mrs2001.9110.1557/mrs2001.91 ↗

66. Pierre, A. C.Hybrid Organic–Inorganic and Composite Materials; Springer, 2020; pp 421–455.10.1007/978-3-030-38144-8_10 ↗

67. 10.3390/pharmaceutics1003011810.3390/pharmaceutics10030118 ↗

68. 10.1016/j.progsolidstchem.2016.01.00110.1016/j.progsolidstchem.2016.01.001 ↗

69. 10.1021/la302145j10.1021/la302145j ↗

70. 10.3390/nano1009179910.3390/nano10091799 ↗

71. 10.1515/zpch-1898-252610.1515/zpch-1898-2526 ↗

72. Mikhnevich G. L. · Phys. Z. Sowjetunion · 1938 · 13 · 20

73. 10.1016/j.jnoncrysol.2006.02.07410.1016/j.jnoncrysol.2006.02.074 ↗

74. 10.1063/1.365669610.1063/1.3656696 ↗

75. 10.1021/cm000607e10.1021/cm000607e ↗

76. 10.1016/j.ceramint.2009.05.03510.1016/j.ceramint.2009.05.035 ↗

77. Cullity B. D. · 1978 · 102

78. 10.1007/s10853-009-3273-610.1007/s10853-009-3273-6 ↗

79. Goodman J. F. · Proc. R. Soc. A · 1958 · 247 · 346

80. 10.1127/0935-1221/01/0013-032910.1127/0935-1221/01/0013-0329 ↗

81. 10.1016/j.colsurfa.2006.11.04810.1016/j.colsurfa.2006.11.048 ↗

82. 10.1016/j.tca.2003.09.00410.1016/j.tca.2003.09.004 ↗

83. 10.1061/(ASCE)0733-9372(1997)123:10(1041)10.1061/(ASCE)0733-9372(1997)123:10(1041) ↗

84. 10.1016/S0141-3910(03)00026-010.1016/S0141-3910(03)00026-0 ↗

85. 10.1016/j.polymdegradstab.2013.09.02610.1016/j.polymdegradstab.2013.09.026 ↗

86. 10.1021/ma021481510.1021/ma0214815 ↗

87. 10.1002/1521-3935(20011201)202:18<3445::AID-MACP3445>3.0.CO;2-N10.1002/1521-3935(20011201)202:18<3445::AID-MACP3445>3.0.CO;2-N ↗

88. Cheng Y. Y. · Polym. Polym. Compos. · 2005 · 13 · 52510.1177/096739110501300509 ↗

89. 10.1016/S0921-5093(04)00857-310.1016/S0921-5093(04)00857-3 ↗