journal article·2020-02-04

Fabrication of Dipole-Aligned Thin Films of Porphyrin J-Aggregates over Large Surfaces

Adam Weissman, Hodaya Klimovsky, Dor Harel, Racheli Ron, Martin Oheim, Adi Salomon

Langmuir· Volume 36· Issue 4
Publisher page

Abstract

We report a new approach for large-scale alignment of micron-sized J-aggregates of a derivative of porphyrin onto planar glass substrates. We applied a unidirectional nitrogen flow to an aqueous dye drop deposited onto a glass substrate to form an about 5 nm thick film of aligned J-aggregates over macroscopic surface areas up to several millimeters. The inter-aggregate distance is ∼500 nm, and it scales with the nitrogen pressure. We verified the film thickness and J-aggregate alignment using multimodal microscopy and spectroscopy techniques. Our technique is fast, simple, and cost-effective for producing large two-dimensional (2-D) arrays of aligned emitters.
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Research context

OpenAlex topics: Spectroscopy and Quantum Chemical Studies · Nonlinear Dynamics and Pattern Formation · Advanced Thermodynamics and Statistical Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Institute of Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 5290002, Israel

Université de Paris, SPPIN − Saints-Pères Paris Institute for the Neurosciences, CNRS, F-75006 Paris, France

Funding

Agence Nationale de la Recherche · Israel Science Foundation · German-Israeli Foundation for Scientific Research and Development · Centre National de la Recherche Scientifique · Horizon 2020 Framework Programme · Ministère des Affaires Étrangères · Region ile de france

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