Attachment of the Sulfonic Acid Group in the Interlayer Space of a Layered Alkali Silicate, Octosilicate
Source abstract
Abstract
The surface modification of a layered alkali silicate, octosilicate (Na(2)Si(8)O(17)·nH2O), with a sulfonic acid group was conducted. The sulfonic acid group was attached to the silicate layer by the reaction of octosilicate with phenethyl(dichloro)methylsilane and the subsequent sulfonation of the attached phenethyl groups with chlorosulfonic acid. The modified octosilicate is a solid acid as indicated by the intercalation of dodecylamine. A systematic expansion of the interlayer space was observed by the ion exchange with a series of alkyltrimethylammonium ions to show the variation of the layer charge density.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Graduate School of Creative Science and Engineering and ‡Department of Earth Sciences, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo 169-8050, Japan
References (40)
Show source-provided references
1. Auerbach S. M. · 200410.1201/9780203021354 ↗
2. Bergaya F. · 2006
3. Barrer R. M. · Clays Clay Miner. · 1984 · 37 · 38510.1346/CCMN.1989.0370501 ↗
4. Okada T. · J. Phys.Chem. C · 2004 · 114 · 53910.1021/jp9089886 ↗
5. Seki Y. · Bull. Chem. Soc. Jpn. · 2010 · 83 · 71210.1246/bcsj.20090191 ↗
6. Takahashi N · J. Mater. Chem. · 2011 · 21 · 1433610.1039/c1jm10460h ↗
7. Lagaly G. · Adv. Colloid Interface Sci. · 1979 · 11 · 10510.1016/0001-8686(79)85001-0 ↗
8. Ogawa M. · Cryst. Growth Des. · 2010 · 10 · 206810.1021/cg900922v ↗
9. Ogawa M. · Chem. Commun. · 2010 · 46 · 224110.1039/b918927k ↗
10. Ruiz-Hitzky E. · Nature · 1980 · 287 · 2810.1038/287028a0 ↗
11. Ogawa M. · J. Am. Chem. Soc. · 1998 · 120 · 736110.1021/ja981055s ↗
12. Osterloh F. E. · J. Am. Chem. Soc. · 2002 · 124 · 624810.1021/ja025858y ↗
13. Fujita I. · Chem. Mater. · 2003 · 15 · 313410.1021/cm011698y ↗
14. Fujita I. · Chem. Mater. · 2005 · 17 · 371710.1021/cm048023q ↗
15. Ide Y. · Angew. Chem., Int. Ed. · 2007 · 46 · 844910.1002/anie.200702360 ↗
16. Ide Y. · Langmuir · 2011 · 27 · 252210.1021/la104436t ↗
17. Ide Y. · Langmuir · 2009 · 25 · 527610.1021/la803967s ↗
18. Van Rhijn W. M. · Chem. Commun. · 1998 · 31710.1039/a707462j ↗
19. Lim M. H. · Chem. Mater. · 1998 · 10 · 46710.1021/cm970713p ↗
20. Melero J. A. · Chem. Rev. · 2006 · 106 · 379010.1021/cr050994h ↗
21. Molnar B. R. A. · J. Mol. Catal. A: Chem. · 2006 · 244 · 57
22. Toda M. · Nature · 2005 · 438 · 17810.1038/438178a ↗
23. Hara M. · Angew. Chem., Int. Ed. · 2004 · 43 · 295510.1002/anie.200453947 ↗
24. Marschall R. · Chem. Mater. · 2007 · 19 · 640110.1021/cm071164i ↗
25. Lee J. B. · J. Power Sources · 2006 · 158 · 125110.1016/j.jpowsour.2005.10.085 ↗
26. Di Giacomo P. M. · Polyhedron · 1982 · 1 · 6110.1016/S0277-5387(00)81070-0 ↗
27. Yang C. Y. · React. Polym. · 1987 · 5 · 13
28. Colbn J. L. · J. Phys. Chem. · 1988 · 92 · 577710.1021/j100331a046 ↗
29. Endo K · Bull. Chem. Soc. Jpn. · 1994 · 67 · 335210.1246/bcsj.67.3352 ↗
30. Ide Y. · Bull. Chem. Soc. Jpn. · 2007 · 80 · 162410.1246/bcsj.80.1624 ↗
31. Ide Y. · Chem. Mater. · 2007 · 19 · 96410.1021/cm062117d ↗
32. Mochizuki D. · J. Am. Chem. Soc. · 2002 · 124 · 1208210.1021/ja027512t ↗
33. Mochizuki D. · J. Am. Chem. Soc. · 2005 · 127 · 718310.1021/ja042194e ↗
34. Mochizuki D. · New J. Chem. · 2006 · 30 · 27710.1039/b514157e ↗
35. Ogawa M. · Chem. Lett. · 2002 · 31 · 63210.1246/cl.2002.632 ↗
36. Sohmiya M. · J. Phys. Chem. B · 2007 · 111 · 883610.1021/jp064654r ↗
37. Okutomo S. · Appl. Clay Sci. · 1999 · 15 · 25310.1016/S0169-1317(99)00010-1 ↗
38. Ide Y. · J. Colloid Interface Sci. · 2005 · 296 · 14110.1016/j.jcis.2005.08.058 ↗
39. Ide Y. · Chem. Lett. · 2005 · 34 · 36010.1246/cl.2005.360 ↗
40. Lagaly G. · Solid State Ionics · 1986 · 22 · 4310.1016/0167-2738(86)90057-3 ↗