Metal–Organic Framework Separator as a Polyselenide Filter for High-Performance Lithium–Selenium Batteries

Md. Anwar Hossain; Sarttrawut Tulaphol; Arjun K. Thapa; Mohammad Shahinur Rahaman; Jacek B. Jasinski; Hui Wang; Mahendra K. Sunkara; Jaroslaw Syzdek; Osman K. Ozdemir; Jason M. Ornstein; Noppadon Sathitsuksanoh

doi:10.1021/acsaem.1c01806

journal article·2021-12-27

Metal–Organic Framework Separator as a Polyselenide Filter for High-Performance Lithium–Selenium Batteries

Md. Anwar Hossain, Sarttrawut Tulaphol, Arjun K. Thapa, Mohammad Shahinur Rahaman, Jacek B. Jasinski, Hui Wang, Mahendra K. Sunkara, Jaroslaw Syzdek, Osman K. Ozdemir, Jason M. Ornstein, Noppadon Sathitsuksanoh

ACS Applied Energy Materials· Volume 4· Issue 12

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Source abstract

Abstract

Rapid self-discharge, poor cycling stability, and low Coulombic efficiency from polyselenide shuttling have retarded practical applications of lithium–selenium batteries. Here, we show that a cation-selective PCN separator of PCN-250(Fe) metal–organic frameworks coated on a porous polypropylene membrane suppresses polyselenide shuttle and enhances lithium-ion transport in lithium–selenium batteries. The Lewis acid sites of this PCN separator acted as selective barriers that immobilized polyselenides and provided uniform and stable lithium nucleation and growth during cycling. Lithium–selenium cells with the PCN separator had a stable and reversible electrochemical performance with a high discharge capacity of 423 mAh/g at C/5 and a Coulombic efficiency of >98% for 500 cycles. This work provides a guide for developing high-performance lithium–selenium batteries by a cation-selective separator strategy. This PCN separator can be applied to alkali-metal and alkali-metal chalcogenide battery systems.

Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, University of Louisville, Louisville, Kentucky 40292, United States

Sustainable Polymer & Innovative Composite Materials Research Group, Department of Chemistry, Faculty of Science, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand

Conn Center for Renewable Energy Research, University of Louisville, Louisville, Kentucky 40292, United States

Department of Mechanical Engineering, University of Louisville, Louisville, Kentucky 40292, United States

Bio-Logic USA LLC, 9050 Executive Park Dr. Ste.110C, Knoxville, Tennessee 37923, United States

Framergy Inc, 800 Raymond Stotzer Parkway, Ste 2011A, College Station, Texas 77845-6371, United States

Funding

University of Louisville · Office of Integrative Activities · Division of Electrical, Communications and Cyber Systems

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