journal article·2021-08-23

Electrochemically inert aluminum cations coordinated with tetrahydroxybenzoquinone toward high-energy storage

Guochun Ding, Limin Zhu, Qing Han, Lingling Xie, Xinli Yang, Xin Li, Lei Chen, Gongke Wang, Fu Sun, Xiaoyu Cao

ACS Applied Energy Materials· Volume 4· Issue 8
Publisher page

Abstract

Organic carbonyl compounds are a kind of promising cathodes in lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) in view of their low cost, structural flexibility, and abundant resources. However, their intrinsic high solubility and low electrical conductivity limit their application. Herein, a novel coordination-driven polymer named aluminum-poly(tetrahydroxybenzoquinone) (PTHBQ-Al) has been synthesized through a facile coordination reaction between tetrahydroxybenzoquinone (THBQ) and aluminum chloride (AlCl3). This polymer exhibited a reversible capacity of 141 mAh g–1 at 100 mA g–1 after 500 cycles in LIBs. Particularly in SIBs, it delivered a reversible capacity of 104 mAh g–1 under the same conditions in ester-based electrolytes. The Coulombic efficiency reached up to 100% in both LIBs and SIBs. In all-organic Li/Na-ion batteries of PTPAn/PTHBQ-Al, reversible charge/discharge capacities of 49/45 and 41/40 mAh g–1 were obtained after 100 cycles at 50 mA g–1, respectively. To classify the reaction mechanism, ex situ FT-IR was further performed. Synchrotron X-ray tomography was used as a nondestructive investigation method to reveal the capacity decay caused by dead lithium/sodium deposition in the anode side, which prevented the transfer of Li+ and Na+ ions and increased the internal battery resistance.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China

Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City, Zhengzhou 450001, P. R. China

School of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P.R. China

College of Chemical and Printing-dyeing Engineering, Henan University of Engineering, Zhengzhou 450007, P. R. China

School of Materials Science and Engineering, Henan Normal University, Xinxiang 453007, P. R. China

Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences, Qingdao 266101, P. R. China

Funding

National Natural Science Foundation of China · Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology, China · Innovative Funds Plan of Henan University of Technology, China · Science and Technology Research Project of Henan Province, China · Zhongyuan Thousand People Plan-The Zhongyuan Youth Talent Support Program (in Science and Technology), China

References (67)

Show source-provided references
1. 10.1002/adma.20170557510.1002/adma.201705575 ↗
2. 10.1021/acsami.9b0336510.1021/acsami.9b03365 ↗
3. 10.1002/er.502010.1002/er.5020 ↗
4. 10.1016/j.enchem.2019.10000310.1016/j.enchem.2019.100003 ↗
5. 10.1016/j.jmst.2021.02.02010.1016/j.jmst.2021.02.020 ↗
6. 10.1007/s12598-020-01503-410.1007/s12598-020-01503-4 ↗
7. 10.1007/s12598-020-01528-910.1007/s12598-020-01528-9 ↗
8. 10.1007/s12598-020-01469-310.1007/s12598-020-01469-3 ↗
9. 10.1021/acsami.9b2343810.1021/acsami.9b23438 ↗
10. 10.1021/acs.chemmater.9b0310910.1021/acs.chemmater.9b03109 ↗
11. 10.1007/s12598-020-01452-y10.1007/s12598-020-01452-y ↗
12. 10.1149/1945-7111/ab882710.1149/1945-7111/ab8827 ↗
13. 10.1016/j.ensm.2019.11.02010.1016/j.ensm.2019.11.020 ↗
14. 10.1016/j.electacta.2020.13613810.1016/j.electacta.2020.136138 ↗
15. 10.1021/acsami.0c1060310.1021/acsami.0c10603 ↗
16. 10.1021/acs.accounts.9b0023110.1021/acs.accounts.9b00231 ↗
17. 10.1016/j.cej.2019.05.00910.1016/j.cej.2019.05.009 ↗
18. 10.1021/acsami.8b0036410.1021/acsami.8b00364 ↗
19. 10.1039/C6CS00173D10.1039/C6CS00173D ↗
20. 10.1002/aenm.20110079510.1002/aenm.201100795 ↗
21. 10.1039/C6TA01069E10.1039/C6TA01069E ↗
22. 10.1016/j.electacta.2020.13568110.1016/j.electacta.2020.135681 ↗
23. 10.1016/j.ensm.2018.06.03010.1016/j.ensm.2018.06.030 ↗
24. 10.1002/adfm.20190959710.1002/adfm.201909597 ↗
25. 10.1002/cssc.20190311210.1002/cssc.201903112 ↗
26. 10.1002/asia.20190134410.1002/asia.201901344 ↗
27. 10.1021/acs.chemmater.9b0260110.1021/acs.chemmater.9b02601 ↗
28. 10.1039/C7QI00453B10.1039/C7QI00453B ↗
29. 10.1016/j.jpowsour.2017.01.07910.1016/j.jpowsour.2017.01.079 ↗
30. 10.1021/acsami.7b1391110.1021/acsami.7b13911 ↗
31. 10.1039/C4EE02575J10.1039/C4EE02575J ↗
32. 10.1039/c3ee40709h10.1039/c3ee40709h ↗
33. 10.1002/anie.20100243910.1002/anie.201002439 ↗
34. 10.1021/nl203966610.1021/nl2039666 ↗
35. 10.1039/D0RA00884B10.1039/D0RA00884B ↗
36. 10.1016/j.electacta.2018.06.03310.1016/j.electacta.2018.06.033 ↗
37. 10.1002/cssc.20170117510.1002/cssc.201701175 ↗
38. 10.1016/j.cej.2018.05.07810.1016/j.cej.2018.05.078 ↗
39. 10.1002/adma.20170386810.1002/adma.201703868 ↗
40. 10.1021/acsmacrolett.8b0015410.1021/acsmacrolett.8b00154 ↗
41. 10.1149/2.0391811jes10.1149/2.0391811jes ↗
42. 10.1002/er.476410.1002/er.4764 ↗
43. 10.1002/advs.20150001810.1002/advs.201500018 ↗
44. 10.1039/C5CC02251G10.1039/C5CC02251G ↗
45. 10.1016/j.electacta.2018.10.07510.1016/j.electacta.2018.10.075 ↗
46. 10.1016/j.jcis.2016.11.01010.1016/j.jcis.2016.11.010 ↗
47. 10.1039/C2CS35407A10.1039/C2CS35407A ↗
48. 10.1021/ja208940u10.1021/ja208940u ↗
49. 10.1016/j.carbon.2019.09.01110.1016/j.carbon.2019.09.011 ↗
50. 10.1016/j.jpowsour.2012.08.04010.1016/j.jpowsour.2012.08.040 ↗
51. 10.1021/jacs.5b0802210.1021/jacs.5b08022 ↗
52. 10.1002/anie.20200925310.1002/anie.202009253 ↗
53. 10.1002/advs.20150012410.1002/advs.201500124 ↗
54. 10.1039/B814515F10.1039/B814515F ↗
55. 10.1039/C3QI00076A10.1039/C3QI00076A ↗
56. 10.1002/cssc.20200018010.1002/cssc.202000180 ↗
57. 10.1002/chem.20100237910.1002/chem.201002379 ↗
58. 10.1002/anie.20131113610.1002/anie.201311136 ↗
59. 10.1016/j.nanoen.2020.10519610.1016/j.nanoen.2020.105196 ↗
60. 10.1021/acsenergylett.6b0058910.1021/acsenergylett.6b00589 ↗
61. 10.1002/smll.20150227810.1002/smll.201502278 ↗
62. 10.1039/C5CC00073D10.1039/C5CC00073D ↗
63. 10.1039/C5CC05654C10.1039/C5CC05654C ↗
64. 10.1039/C5TA02043C10.1039/C5TA02043C ↗
65. 10.1038/srep0267110.1038/srep02671 ↗
66. 10.1021/acssuschemeng.8b0050010.1021/acssuschemeng.8b00500 ↗
67. 10.1002/anie.20140003210.1002/anie.201400032 ↗