journal article·2019-04-22

Polymer-Bound DuBois-Type Molecular H2 Oxidation Ni Catalysts Are Protected by Redox Polymer Matrices

Adrian Ruff, Salome Janke, Julian Szczesny, Sabine Alsaoub, Ines Ruff, Wolfgang Lubitz, Wolfgang Schuhmann

ACS Applied Energy Materials· Volume 2· Issue 4
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Abstract

The immobilization, protection, and electrical wiring of sensitive catalysts by specifically designed supporting matrixes are of particular importance for technological relevant applications. Here, we describe the protection of a DuBois-type H2 oxidation catalyst, which was covalently bound to an inert polymer matrix, against molecular O2 by forming blends together with an O2-reducing redox polymer matrix. This matrix simultaneously acts as an electron relay for shuttling electrons between the catalyst and the electrode.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · CO2 Reduction Techniques and Catalysts

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Analytical Chemistry - Center for Electrochemical Sciences (CES), Faculty of Chemistry and Biochemistry, Ruhr University Bochum, Universitätsstrasse 150, 44780 Bochum, Germany

Thermo Fisher Scientific, Im Steingrund 4-6, 63303 Dreieich, Germany

Max-Planck-Institut für Chemische Energiekonversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany

Funding

Agence Nationale de la Recherche · Deutsche Forschungsgemeinschaft

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