journal article·2016-11-22Open access

Effect of Porosity on the Thick Electrodes for High Energy Density Lithium Ion Batteries for Stationary Applications

Madhav Singh, Jörg Kaiser, Horst Hahn

Batteries· Volume 2· Issue 4

Abstract

A series of 250–350 μ m-thick single-sided lithium ion cell graphite anodes and lithium nickel manganese cobalt oxide (NMC) cathodes with constant area weight, but varying porosity were prepared. Over this wide thickness range, micron-sized carbon fibers were used to stabilize the electrode structure and to improve electrode kinetics. By choosing the proper porosities for the anode and cathode, kinetic limitations and aging losses during cell cycling could be minimized and energy density improved. The cell (C38%-A48%) exhibits the highest energy density, 441 Wh/L at the C/10 rate, upon cycling at elevated temperature and different C-rates. The cell (C38%-A48%) showed 9% higher gravimetric energy density at C/10 in comparison to the cell with as-coated electrodes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced Battery Materials and Technologies

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Affiliations

Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Project Competence-E, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU), Albert-Einstein-Allee 11, 89081 Ulm, Germany

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