journal article·2021-07-26

Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays

Hong-Lin Zhu, Lin-Chang Liu, Zhong-Yi Li, Jing-Jing Ma, Yue-Qing Zheng, Miao Shui

ACS Applied Energy Materials· Volume 4· Issue 7
Publisher page

Abstract

Electrocatalytic CO2 reduction into value-added fuels is a promising and economical strategy to mitigate CO2 emissions. Herein, a self-supported cobalt phthalocyanine anchored on chrysanthemum-like ZnIn2S4 nanoarray electrode was prepared. By integration of experimental analysis and density functional theory calculation, the CoPc molecule was anchored with hexagonal ZnIn2S4 (ZIS) via S–C and Co–S interaction. The active site for CO2RR in ZIS-CoPc was attributed to Co sites. For hydrogen evolution reaction, the active site was mainly ascribed to the S site on the surface of ZIS.
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Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Electrocatalysts for Energy Conversion · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chemistry Institute for Synthesis and Green Application, School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China

Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

School of Microelectronic Science and Engineering, Ningbo University, Ningbo 315211, China

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