journal article·2018-05-29

Platinum Cluster/Nanoparticle on CoO Nanosheets with Coupled Atomic Structure and High Electrocatalytic Durability

H.-J. Qiu, J. J. Gao, Y. R. Wen, B. Shang, J. Q. Wang, Xi Lin, Y. Wang

ACS Applied Energy Materials· Volume 1· Issue 5
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Abstract

Seeking electrocatalysts with a low Pt content, high activity, and durability in oxygen reduction reaction (ORR) remains one major challenge for fuel cell applications. Herein, by chemical dealloying of AlCoPt ternary alloys, CoO nanosheets with evenly doped ultrasmall Pt clusters/nanoparticles have been obtained. Thanks to the coherent atomic structure between CoO and Pt, the Pt-doped CoO (Pt/CoO) can work stably for ORR in 0.1 M HClO4 after tens of thousands of electrochemical cycles and exhibits a 13.5-fold enhancement in the electrochemically active surface area normalized ORR activity over that of commercial Pt/C catalyst.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Nanoporous metals and alloys · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, Congqing University, Chongqing 400044, China

School of Materials Science and Engineering, Harbin Institute of Technology, Shenzhen 518055, China

Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Funding

Chongqing University · Chongqing Science and Technology Commission · National Natural Science Foundation of China · State Key Laboratory of Mechanical Transmission, Chongqing University · Central People's Government of the People's Republic of China

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