DataVXACS Applied Energy MaterialsPaper
journal article·2020-03-23Open access

Scalable Route to Electroactive and Light Active Perylene Diimide Dye Polymer Binder for Lithium-Ion Batteries

Pierre Ranque, Chandramohan George, Rajeev K. Dubey, Remco van der Jagt, Delphine Flahaut, Rémi Dedryvère, Marcus Fehse, Panagiotis Kassanos, Wolter F. Jager, Ernst J. R. Sudhölter, Erik M. Kelder

ACS Applied Energy Materials· Volume 3· Issue 3
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Source abstract

Abstract

Developing multifunctional polymeric binders is key to the design of energy storage technologies with value-added features. We report that a multigram-scale synthesis of perylene diimide polymer (PPDI), from a single batch via polymer analogous reaction route, yields high molecular weight polymers with suitable thermal stability and minimized solubility in electrolytes, potentially leading to improved binding affinity toward electrode particles. Further, it develops strategies for designing copolymers with virtually any desired composition via a subsequent grafting, leading to purpose-built binders. PPDI dye as both binder and electroactive additive in lithium half-cells using lithium iron phosphate exhibits good electrochemical performance.
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Research context

Energy storagePolymers

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Applied Sciences, Department of Chemical Engineering (OMI-ChemE), Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands

Institut des Sciences Analytiques et de Physicochimie pour l’Environnement et les Matériaux, IPREM, E2S-UPPA/CNRS/Université Pau & Pays Adour, 64000 Pau, France

ALISTORE-ERI European Research Institute, 33 rue Saint Leu, 80000 Amiens, France

Dyson School of Design Engineering, Imperial College London, SW7 2AZ London, United Kingdom

Department of Radiation Science and Technology/Reactor Institute Delft, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands

Dutch-Belgian (DUBBLE), ESRF-The European Synchrotron, CS 40220, 38043 Cedex 9 Grenoble, France

The Hamlyn Centre, Imperial College London, SW7 2AZ London, United Kingdom

Funding

Conseil National de la Recherche Scientifique · H2020 Marie Sklodowska-Curie Actions · Nederlandse Organisatie voor Wetenschappelijk Onderzoek · Alistore-European Research Institute

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