Z-Scheme Transfer Path of Charges in the BiVO₄/Bi:ZnIn₂S₄-Co Photoanode for Photoelectrochemical Water Splitting

The significant carrier recombination occurring in the bulk of BiVO 4 is a primary factor limiting the enhancement of its photoelectrochemical performance. To address this issue, we have incorporated two-dimensional (2D) nanosheet morphology Bi:ZnIn 2 S 4 and Co sites onto the surface of BiVO 4 to create an effective composite photoanode. According to the ultraviolet-visible diffuse reflectance spectroscopy and ultraviolet photoelectron spectroscopy results, it was inferred that a Z-scheme transfer path of charges was formed between BiVO 4 and Bi:ZnIn 2 S 4, which promoted the separation of bulk phase carriers. Additionally, the 2D topography of Bi:ZnIn 2 S 4 also shortens the transmission distance of the carriers. Furthermore, the presence of Co sites provides more active sites for the surface hydrolysis reaction to proceed. Ultimately, under AM1.5G illumination, the photocurrent density of the BiVO 4 /Bi:ZnIn 2 S 4 -Co photoanode reaches 3.6 mA cm –2 at 1.23 V vs reversible hydrogen electrodes.