journal article·2024-10-14

Facile Top-Down Synthesis of Phase-Pure and Tunable Bandgap CuBi2O4 Photocathode Materials by Low-Energy Sequential Ball Milling

Syed Farid Uddin Farhad, Mst. Irin Naher, Nazmul Islam Tanvir, Md. Saiful Quddus, Shirin Akter Jahan, Md Aftab Ali Shaikh

ACS Applied Energy Materials· Volume 7· Issue 19
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Abstract

A facile synthesis process has been developed for the large-scale production of bismuth cuprate (CuBi 2 O 4 ) for attaining a high solar-to-hydrogen production efficiency via photoelectrochemical water splitting. Here we attempt to synthesize phase-pure CuBi 2 O 4 nanopowders using a modified solid-state reaction technique, subsequently sintered at ∼750 °C for 4 h in air. These pristine CuBi 2 O 4 (CBO) powders have been further sequentially ball-milled (SBM) up to 25 h to elucidate the milling duration effect on the optical bandgap of the ball-milled CuBi 2 O 4 (SBM-CBO). (Photo)electrochemical studies of drop-casted SBM-CBO/fluorine-doped SnO 2 rudimentary electrodes suggest their suitability as visible-light-responsive photocathode materials for sunlight-driven hydrogen production.
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Research context

OpenAlex topics: Electronic and Structural Properties of Oxides · Copper-based nanomaterials and applications · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Energy Conversion and Storage Research Section, Industrial Physics Division, BCSIR Dhaka Laboratories, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka 1205, Bangladesh

Central Analytical and Research Facilities, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka 1205, Bangladesh

Institute of Glass and Ceramic Research and Testing, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka 1205, Bangladesh

Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka 1205, Bangladesh

Funding

Ministry of Science and Technology, Government of the People?s Republic of Bangladesh · Bangladesh Council of Scientific and Industrial Research · Royal Society of Chemistry · The World Academy of Sciences

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