Antiflooding Gas Diffusion Electrodes Enabled by Liquid–Solid–Liquid Interfaces for Durable CO₂ Electrolysis

Gas diffusion electrodes (GDEs) show great potential to improve the current densities of the industrial electrochemical carbon dioxide reduction reaction (eCO 2 RR). The triple-phase boundary (TPB) in GDEs is the key for promoted reaction kinetics, yet such a reaction interface typically suffers from rapid degradation due to electrolyte flooding and salt precipitation. Herein, we demonstrate that a GDE modified with liquid perfluorocarbon (PFC) would notably prolong the lifespan of the GDE with a Bi catalyst in flow-cell electrolyzers. PFC with superhydrophobicity and high CO 2 solubility would construct a liquid–solid–liquid reaction interface that prevents the intrusion of electrolytes into the microporous layer (MPL) without hampering the mass transport of CO 2 . Our work demonstrates an effective strategy to construct a robust and efficient electrochemical reaction interface for the eCO 2 RR with improved stability for potential industrial applications.