Halide Lithium Conductors: From Design and Synthesis to Application for All-Solid-State Batteries
Source abstract
Abstract
All-solid-state lithium batteries (ASSLBs) based on solid-state electrolytes (SSEs) are considered as the next generation of energy storage devices due to their high energy density and safety. Halide SSEs have attracted attention due to their high oxidative stability, compatibility with oxide cathodes, and high ionic conductivity (>10 –3 S·cm –1 ). Here, we introduce various halide SSEs and common synthesis methods. To design halide SSEs, we discuss the challenges faced by halide SSEs in terms of ion transport and electrochemical stability and present corresponding optimization strategies. Subsequently, the application of halide SSEs in high-specific-energy ASSLBs is demonstrated. Finally, we propose the key issues that need to be addressed and perspectives on future research of halide SSEs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P.R. China
Funding
Graduate Research and Innovation Projects of Jiangsu Province · National Key Research and Development Program of China · Jiangsu Provincial Department of Science and Technology · National Natural Science Foundation of China · Science and technology innovation fund for emission peak and carbon neutrality of Jiangsu province
References (100+)
Show source-provided references
1. 10.1126/science.121274110.1126/science.1212741 ↗
2. 10.1038/natrevmats.2016.1310.1038/natrevmats.2016.13 ↗
3. 10.1038/nenergy.2016.14110.1038/nenergy.2016.141 ↗
4. 10.1002/ange.20230780210.1002/ange.202307802 ↗
5. 10.1038/s41560-024-01565-z10.1038/s41560-024-01565-z ↗
6. 10.1021/acs.chemrev.2c0037410.1021/acs.chemrev.2c00374 ↗
7. 10.1126/sciadv.abn437210.1126/sciadv.abn4372 ↗
8. 10.1002/advs.20230860410.1002/advs.202308604 ↗
9. 10.1021/acs.energyfuels.0c0264710.1021/acs.energyfuels.0c02647 ↗
10. 10.1149/1.185085410.1149/1.1850854 ↗
11. 10.1038/s41467-024-46472-910.1038/s41467-024-46472-9 ↗
12. 10.1002/adma.20170570210.1002/adma.201705702 ↗
13. 10.1039/D0TA08590A10.1039/D0TA08590A ↗
14. 10.1002/ente.20220128810.1002/ente.202201288 ↗
15. 10.1038/nmat306610.1038/nmat3066 ↗
16. 10.1002/aenm.20180003510.1002/aenm.201800035 ↗
17. 10.1002/adma.20190113110.1002/adma.201901131 ↗
18. 10.1038/s41570-023-00541-710.1038/s41570-023-00541-7 ↗
19. 10.1021/ja01367a00610.1021/ja01367a006 ↗
20. 10.1002/recl.1950069120310.1002/recl.19500691203 ↗
21. 10.1016/0375-9601(76)90087-610.1016/0375-9601(76)90087-6 ↗
22. 10.1149/1.213323810.1149/1.2133238 ↗
23. 10.1149/1.206944610.1149/1.2069446 ↗
24. 10.1016/0025-5408(81)90099-410.1016/0025-5408(81)90099-4 ↗
25. 10.1016/0025-5408(84)90105-310.1016/0025-5408(84)90105-3 ↗
26. 10.1016/0022-3697(81)90142-610.1016/0022-3697(81)90142-6 ↗
27. 10.1246/cl.1998.22310.1246/cl.1998.223 ↗
28. 10.1002/zaac.1992613010410.1002/zaac.19926130104 ↗
29. 10.1016/0167-2738(89)90040-410.1016/0167-2738(89)90040-4 ↗
30. 10.1021/ic00017a01910.1021/ic00017a019 ↗
31. 10.1002/zaac.1997623071010.1002/zaac.19976230710 ↗
32. 10.1002/zaac.1997623090510.1002/zaac.19976230905 ↗
33. 10.1246/bcsj.70.240510.1246/bcsj.70.2405 ↗
34. 10.1016/j.ssi.2006.06.02610.1016/j.ssi.2006.06.026 ↗
35. 10.1002/adma.20180307510.1002/adma.201803075 ↗
36. 10.1039/C9EE02311A10.1039/C9EE02311A ↗
37. 10.1021/jacs.0c0013410.1021/jacs.0c00134 ↗
38. 10.1038/s41467-021-24697-210.1038/s41467-021-24697-2 ↗
39. 10.1002/adfm.20240857110.1002/adfm.202408571 ↗
40. 10.1149/1.241231210.1149/1.2412312 ↗
41. 10.1149/1.240835110.1149/1.2408351 ↗
42. 10.1016/0022-3697(69)90174-710.1016/0022-3697(69)90174-7 ↗
43. 10.1246/cl.1989.22310.1246/cl.1989.223 ↗
44. 10.1016/0167-2738(83)90223-010.1016/0167-2738(83)90223-0 ↗
45. 10.1002/bbpc.1984088081010.1002/bbpc.19840880810 ↗
46. 10.1016/0022-4596(87)90159-910.1016/0022-4596(87)90159-9 ↗
47. 10.1016/0025-5408(81)90142-210.1016/0025-5408(81)90142-2 ↗
48. 10.1149/1.211561110.1149/1.2115611 ↗
49. 10.1149/1.210870410.1149/1.2108704 ↗
50. 10.1246/cl.1987.146510.1246/cl.1987.1465 ↗
51. 10.1016/0022-4596(87)90159-910.1016/0022-4596(87)90159-9 ↗
52. 10.1002/zaac.1987553102010.1002/zaac.19875531020 ↗
53. 10.1515/znb-1989-091010.1515/znb-1989-0910 ↗
54. 10.1016/0022-4596(90)90050-810.1016/0022-4596(90)90050-8 ↗
55. 10.1016/0167-2738(93)90245-X10.1016/0167-2738(93)90245-X ↗
56. 10.1107/S056774087500811410.1107/S0567740875008114 ↗
57. 10.1016/0167-2738(85)90132-810.1016/0167-2738(85)90132-8 ↗
58. 10.1016/0022-4596(88)90301-510.1016/0022-4596(88)90301-5 ↗
59. 10.1016/0022-4596(88)90040-010.1016/0022-4596(88)90040-0 ↗
60. 10.1006/jssc.1996.023910.1006/jssc.1996.0239 ↗
61. 10.1016/S0022-3697(96)00082-010.1016/S0022-3697(96)00082-0 ↗
62. 10.1038/s41467-023-43886-910.1038/s41467-023-43886-9 ↗
63. 10.1021/acsenergylett.3c0230710.1021/acsenergylett.3c02307 ↗
64. 10.1016/j.jssc.2005.04.03810.1016/j.jssc.2005.04.038 ↗
65. 10.5796/electrochemistry.23-0000510.5796/electrochemistry.23-00005 ↗
66. 10.1088/0953-8984/16/43/01710.1088/0953-8984/16/43/017 ↗
67. 10.1016/j.xcrp.2023.10142810.1016/j.xcrp.2023.101428 ↗
68. 10.1021/acs.inorgchem.8b0045810.1021/acs.inorgchem.8b00458 ↗
69. 10.1038/s41557-024-01634-610.1038/s41557-024-01634-6 ↗
70. 10.1016/j.isci.2019.05.03610.1016/j.isci.2019.05.036 ↗
71. 10.1021/acsaem.0c0014710.1021/acsaem.0c00147 ↗
72. 10.1021/acs.nanolett.1c0357310.1021/acs.nanolett.1c03573 ↗
73. 10.1002/aenm.20210392110.1002/aenm.202103921 ↗
74. 10.1107/S056774086800200110.1107/S0567740868002001 ↗
75. 10.1149/2.012206eel10.1149/2.012206eel ↗
76. 10.1021/acsaem.9b0116610.1021/acsaem.9b01166 ↗
77. 10.1142/9789812776259_007310.1142/9789812776259_0073 ↗
78. 10.1002/anie.20190980510.1002/anie.201909805 ↗
79. 10.1021/acsenergylett.1c0054510.1021/acsenergylett.1c00545 ↗
80. 10.1002/advs.20220463310.1002/advs.202204633 ↗
81. 10.1038/s41467-023-42538-210.1038/s41467-023-42538-2 ↗
82. 10.1038/s41467-023-37122-710.1038/s41467-023-37122-7 ↗
83. 10.1002/adma.20240527710.1002/adma.202405277 ↗
84. 10.1134/S106377451003013210.1134/S1063774510030132 ↗
85. 10.1126/sciadv.abh189610.1126/sciadv.abh1896 ↗
86. 10.1002/aenm.20190371910.1002/aenm.201903719 ↗
87. 10.1002/smtd.20210100210.1002/smtd.202101002 ↗
88. 10.1002/aenm.20200319010.1002/aenm.202003190 ↗
89. 10.1021/acs.nanolett.2c0018710.1021/acs.nanolett.2c00187 ↗
90. 10.1246/cl.22054010.1246/cl.220540 ↗
91. 10.1002/aenm.20240255510.1002/aenm.202402555 ↗
92. 10.1016/0022-5088(81)90132-610.1016/0022-5088(81)90132-6 ↗
93. 10.1002/zaac.1994620031210.1002/zaac.19946200312 ↗
94. 10.1021/jacs.5b1185110.1021/jacs.5b11851 ↗
95. 10.1002/cphc.20039006010.1002/cphc.200390060 ↗
96. 10.1002/aenm.20170097110.1002/aenm.201700971 ↗
97. 10.1021/ja305709z10.1021/ja305709z ↗
98. 10.1039/C3TA15087A10.1039/C3TA15087A ↗
99. 10.1103/PhysRevB.87.13430310.1103/PhysRevB.87.134303 ↗
100. 10.1021/cm503717e10.1021/cm503717e ↗