journal article·2020-12-22

Pd Nanoparticle-Decorated Hydrogen Plasma-Treated TiO2 for Photoelectrocatalysis-Based Solar Energy Devices

Deepanjana Adak, Poulomi Chakrabarty, Pavel Majumdar, Rabibrata Mukherjee, Snehangshu Patra, Anup Mondal, Sekhar Bhattacharyya, Hiranmay Saha, Raghunath Bhattacharyya

ACS Applied Electronic Materials· Volume 2· Issue 12
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Abstract

A relatively less explored plasmonic material, Pd, on the TiO2 interface has been utilized to boost the catalytic efficiency of rutile TiO2 as a photoelectrocatalyst material. To obtain desired plasmonic behavior, Pd ions deposited over TiO2 were reduced under cold/nonthermal hydrogen plasma, for complete reduction of as-deposited Pd ions to metallic Pd nanoparticles. The Pd@TiO2 photocatalyst, thus prepared, was then extensively characterized. We emphasize that this particular catalyst can be used as a photoelectrocatalyst, as this is found to exhibit promising photoelectrochemical behavior and its ability as a water oxidation catalyst in water splitting devices. The enhanced catalytic activity achieved by using Pd nanoparticles and subsequent cold hydrogen plasma treatment of Pd@TiO2 is expected to make such a system useful for many other electrocatalytic and related applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre of Excellence for Green Energy and Sensor Systems, Indian Institute of Engineering Science and Technology, Shibpur, Howrah, West Bengal 711103, India

Instability and Soft Patterning Laboratory, Department of Chemical Engineering, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India

Department of Chemistry, The University of Utah, Salt Lake City, Utah 84112, United States

Department of Chemistry, Indian Institute of Engineering Science and Technology, Shibpur, Howrah, West Bengal 711103, India

Core Laboratories, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia

Funding

Department of Science and Technology, Ministry of Science and Technology

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