journal article·2022-05-23

Evidence of Intrinsic Pseudocapacitive Lithium Intercalation in Rutile TiNbO4

Sang-eun Bak, Woowon Chung, Muhammad A. Abbas, Jin Ho Bang

ACS Applied Energy Materials· Volume 5· Issue 5
Publisher page

Abstract

TiNbO4 is a recently discovered Li host material. Unlike most mixed oxides of Ti and Nb, TiNbO4 does not show a phase transformation for Li storage. It stores Li-ions via a purely single-phase reaction. In this work, we show that TiNbO4 stores Li-ions via intercalation pseudocapacitance in both bulk and nanostructured states. The rate performance and capacity of TiNbO4 are independent of nanostructuring, indicating that TiNbO4 stores charges through an intrinsic pseudocapacitance mechanism.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Bionano Technology, Hanyang University, 55 Hanyangdaehak-ro, Sangnok-gu, Ansan, Gyeonggi-do 15588, Republic of Korea

Nanosensor Research Institute, Hanyang University, 55 Hanyangdaehak-ro, Sangnok-gu, Ansan, Gyeonggi-do 15588, Republic of Korea

Department of Chemical and Molecular Engineering and Department of Applied Chemistry, Center for Bionano Intelligence Education and Research, Hanyang University, 55 Hanyangdaehak-ro, Sangnok-gu, Ansan, Gyeonggi-do 15588, Republic of Korea

Funding

National Research Foundation of Korea

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