journal article·2023-03-10Open access

Solid Electrolytes in the N-Propyl-N-methyl-pyrrolidinium Tetrafluoroborate—Lithium Tetrafluoroborate System

Artem Ulihin, Dmitry Novozhilov, Nikolai Uvarov

Batteries· Volume 9· Issue 3

Abstract

Solid electrolytes prepared by the addition of LiBF4 to the plastic phase of [N13pyr]BF4 were prepared, and their physical and electrical properties were investigated. The electrolytes [N13pyr]BF4-LiBF4 containing 8–20 wt% LiBF4 are solid at temperatures below 80 °C and have a high ionic conductivity ~10−3–10−2 S cm−1 at 60 °C. Based on the results of DSC and conductivity studies, the phase diagram of the [N13pyr]BF4-LiBF4 binary system was plotted, and the formation of a new compound, 3[N13pyr]BF4·2LiBF4 was proposed. The existence of the new phase was supported by X-ray diffraction data. Electrochemical measurements of cells with lithium electrodes were carried out to test the applicability of these materials in lithium batteries. The electrochemical window was determined to be more than 5 V. In contrast to earlier data obtained for similar systems, the preconditioning effect was not observed. Nevertheless, the solid electrolyte [N13pyr]BF4-LiBF4 system has high ionic conductivity and may be used in solid-state lithium-ion batteries.
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Research context

OpenAlex topics: Inorganic Fluorides and Related Compounds · Advancements in Battery Materials · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Solid State Chemistry and Mechanochemistry SB RAS, Kutateladze Str., 18, Novosibirsk 630090, Russia

Department of Natural Scences, Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia

Funding

Russian Science Foundation

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