journal article·2022-05-23

High-Performance Battery Separator Made by Thermally Activated Metal–Organic Frameworks

Chen Zhang, Xinru Li, Haiping Wu, Jinhui Xu, Zhibin Qu, Fei Sun, Yue Tian, Fan Li, Li Shen, Yunfeng Lu

ACS Applied Energy Materials· Volume 5· Issue 5
Publisher page

Abstract

High-performance separators for lithium-ion batteries demand high thermal stability and ion-selectivity for lithium-ions. In this work, metal–organic frameworks containing unsaturated open metal sites were used as thermally stable separator materials, conferring electrolytes with increased ionic conductivity (from 0.1 to 0.5 mS cm–1), improved lithium-ion transference number (from 0.42 to 0.77), and enhanced electrochemical stability (>5 V vs Li+/Li).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, 420 Westwood Plaza, Los Angeles, California 90095, United States

School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China

The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, China

Funding

UCLA-HK Center for Graphene Technology and Energy Storage

References (31)

Show source-provided references
1. 10.1039/C4EE01432D10.1039/C4EE01432D ↗
2. 10.1016/j.jpowsour.2006.10.06510.1016/j.jpowsour.2006.10.065 ↗
3. 10.1038/s41560-018-0295-910.1038/s41560-018-0295-9 ↗
4. 10.1126/sciadv.aas982010.1126/sciadv.aas9820 ↗
5. 10.1002/smll.20170300110.1002/smll.201703001 ↗
6. 10.1021/acs.nanolett.5b0073910.1021/acs.nanolett.5b00739 ↗
7. 10.1039/C7SC00668C10.1039/C7SC00668C ↗
8. 10.1021/acs.nanolett.0c0191010.1021/acs.nanolett.0c01910 ↗
9. 10.1002/chem.20150231710.1002/chem.201502317 ↗
10. 10.1039/C6CC03015G10.1039/C6CC03015G ↗
11. 10.1039/C8RE00228B10.1039/C8RE00228B ↗
12. 10.1021/acs.inorgchem.8b0104410.1021/acs.inorgchem.8b01044 ↗
13. 10.1038/s41557-018-0171-z10.1038/s41557-018-0171-z ↗
14. 10.1021/ja507119n10.1021/ja507119n ↗
15. 10.1002/smtd.20180020310.1002/smtd.201800203 ↗
16. 10.1021/jacs.9b0789110.1021/jacs.9b07891 ↗
17. 10.1002/adma.20180833810.1002/adma.201808338 ↗
18. 10.1002/adma.20170747610.1002/adma.201707476 ↗
19. 10.1039/C8NH00342D10.1039/C8NH00342D ↗
20. 10.1002/chem.20180309410.1002/chem.201803094 ↗
21. 10.1016/S1872-2067(19)63291-210.1016/S1872-2067(19)63291-2 ↗
22. 10.1021/jacs.7b0863210.1021/jacs.7b08632 ↗
23. 10.1021/acs.iecr.0c0268310.1021/acs.iecr.0c02683 ↗
24. 10.1016/j.electacta.2011.02.02510.1016/j.electacta.2011.02.025 ↗
25. 10.1002/adma.20210778710.1002/adma.202107787 ↗
26. 10.1039/D0CC04232C10.1039/D0CC04232C ↗
27. 10.1016/j.electacta.2004.01.09010.1016/j.electacta.2004.01.090 ↗
28. 10.1016/S0378-7753(98)00242-010.1016/S0378-7753(98)00242-0 ↗
29. 10.1021/acsenergylett.7b0079210.1021/acsenergylett.7b00792 ↗
30. 10.1021/acsaem.0c0204410.1021/acsaem.0c02044 ↗
31. 10.1016/j.jechem.2020.04.01310.1016/j.jechem.2020.04.013 ↗