journal article·2019-06-01Open access

Synthesis and Electrochemical Performance of Ni-Doped VO2(B) as a Cathode Material for Lithium Ion Batteries

Qian Yang, Zhengguang Zou, Xingyu Wu, Shengyu Li, Yanjiao Zhang

Batteries· Volume 5· Issue 2

Abstract

Ni-doped VO2(B) samples (NixVO2(B)) were fabricated by a facile one-step hydrothermal method. When evaluated as a cathode material for lithium ion batteries (LIBs), these Ni-doped VO2(B) exhibited improved lithium storage performance as compared to the pure VO2(B). In particular, when the doping amount is 3%, NixVO2(B) showed the highest lithium storage capacity, best cycling stability, smallest electrochemical reaction resistance, and largest lithium diffusion coefficient. For example, after 100 cycles at a current density of 32.4 mA/g, NixVO2(B) delivered a high specific discharge capacity of 163.0 mAh/g, much higher than that of the pure VO2(B) sample (95.5 mAh/g). Therefore, Ni doping is an effective strategy for enhancing the lithium storage performance of VO2(B).
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Transition Metal Oxide Nanomaterials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials Science and Engineering, Guilin University of Technology, Guilin 541000, China

References (28)

Show source-provided references
1. In situ methods for Li-ion battery research: A review of recent developments10.1016/j.jpowsour.2015.04.084 ↗
2. The Li-ion rechargeable battery: A perspective10.1021/ja3091438 ↗
3. A review of Ni-based layered oxides for rechargeable Li-ion batteries10.1039/C6TA07991A ↗
4. Electrochemical energy storage for green grid10.1021/cr100290v ↗
5. Cathode materials for magnesium and magnesium-ion based batteries10.1016/j.ccr.2014.11.005 ↗
6. High-surface vanadium oxides with large capacities for lithium-ion batteries: from hydrated aerogel to nanocrystalline VO2(B), V6O13 and V2O510.1039/c1jm11523e ↗
7. High capacity and excellent cyclability of vanadium (IV) oxide in lithium battery applications10.1016/j.elecom.2008.12.017 ↗
8. Superior sodium storage of novel VO2 nano-microspheres encapsulated into crumpled reduced graphene oxide10.1039/C6TA10309J ↗
9. VO2 nanowires assembled into hollow microspheres for high-rate and long-life lithium batteries10.1021/nl500915b ↗
10. Synthesis of VO2 (B) nanorods for Li battery application10.1016/j.cap.2009.01.012 ↗
11. Nanoscroll Buffered Hybrid Nanostructural VO2 (B) Cathodes for High-Rate and Long-Life Lithium Storage10.1002/adma.201205185 ↗
12. Facile synthesis of VO2 (B)/carbon nanobelts with high capacity and good cyclability10.1016/j.jpowsour.2011.10.067 ↗
13. Hydrothermal synthesis of carbon/vanadium dioxide core–shell microspheres with good cycling performance in both organic and aqueous electrolytes10.1016/j.electacta.2009.12.017 ↗
14. Study on the action mechanism of doping transitional elements in spinel LiNi0. 5Mn1. 5O410.1016/j.electacta.2016.05.073 ↗
15. Synthesis of a Co–Ni doped LiMn2O4 spinel cathode material for high-power Li-ion batteries by a sol–gel mediated solid-state route10.1016/j.jallcom.2015.03.243 ↗
16. Hydrothermal Synthesis and Electrochemical Performance of Al-doped VO2(B) as Cathode Materials for Lithium-Ion Battery10.20964/2017.06.59 ↗
17. Synthesis and electrochemical performance of Ag- doped VO2(B) as cathode materials
18. Ni-doping to improve the performance of LiFeBO3/C cathode material for lithium-ion batteries10.1016/j.jallcom.2017.11.365 ↗
19. Synthesis and electrochemical performance of Ni doped Na3V2(PO4)3/C cathode materials for sodium ion batteries10.1016/j.jallcom.2017.09.020 ↗
20. Ni-doped MnO2/CNT nanoarchitectures as a cathode material for ultra-long life magnesium/lithium hybrid ion batteries10.1016/j.mtener.2018.08.010 ↗
21. A new method for preparing lithiated vanadium oxides and their electrochemical performance in secondary lithium batteries10.1016/S0378-7753(98)00042-1 ↗
22. Electrochemical Properties of Al3+/Cl− Doped-0.2Li2MnO3·0.8LiNiO2 Cathode Materials for Lithium-Ion Batteries10.1166/jnn.2018.14550 ↗
23. The amorphous oxides MnV2O6 + δ (0 < δ < 1) as high capacity negative electrode materials for lithium batteries10.1016/S0378-7753(96)02576-1 ↗
24. Electrochemical cycled structure of MnV2O6 nanoribbons synthesized via hydrothermal route
25. MoO2 synthesized by reduction of MoO3 with ethanol vapor as an anode material with good rate capability for the lithium ion battery10.1016/j.jpowsour.2007.12.099 ↗
26. A CNT@ MoSe2 hybrid catalyst for efficient and stable hydrogen evolution10.1039/C5NR05739F ↗
27. Kinetic study on LiFePO4/C nanocomposites synthesized by solid state technique10.1016/j.jpowsour.2005.10.098 ↗
28. The Applications of EIS in the Research of LiFePO4 as the Cathode Materials of Li-ion Batteries