journal article·2021-12-27

Lithium Storage Performance and Investigation of Electrochemical Mechanism of Cobalt Vanadate Nanowires Assembled by Nanosheets

Lang Zhang, Yidan Luo, Ruifang Zhang, Dong Fang, Taofang Zeng, Hongen Wang, Jianhong Yi

ACS Applied Energy Materials· Volume 4· Issue 12
Publisher page

Abstract

Cobalt vanadate (Co3V2O8, CVO) nanowires assembled by nanosheets are successfully synthesized using a two-step hydrothermal method. Annealing temperatures can alter the specific surface area of the CVO samples. The physicochemical and electrochemical properties of these CVO samples are systematically characterized and compared. Impressively, the as-prepared CVO exhibits a higher reversible specific capacity and better rate performance than other annealed CVO electrodes, including a specific capacity of 1810 mAh g–1 at 200 mA g–1 over 50 cycles. Density functional theory computations indicate that the binding energy of CVO decreases after adsorbing Li atoms, leading to a high pseudocapacitance contribution of the electrodes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

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Affiliations

Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, People’s Republic of China

Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts MA02139, United States

College of Physics and Electronic Information, Yunnan Key Laboratory of Optoelectronic Information Technology, Yunnan Normal University, 650500 Kunming, Yunnan, People’s Republic of China

Funding

Henan Province · Yunnan Province

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