journal article·2023-05-18Open access

Model-Based Analysis and Optimization of Acidic Tin–Iron Flow Batteries

Fuyu Chen, Ying Wang, Ying Shi, Hui Chen, Xinzhi Ma, Qinfang Zhang

Batteries· Volume 9· Issue 5

Abstract

Acidic tin–iron flow batteries (TIFBs) employing Sn/Sn2+ and Fe2+/Fe3+ as active materials are regarded as promising energy storage devices due to their superior low capital cost, long lifecycle, and high system reliability. In this paper, the performance of TIFBs is thoroughly investigated via a proposed dynamic model. Moreover, their design and operational parameters are comprehensively analyzed. The simulation results show that (i) a flow factor of two is favorable for practical TIFBs; (ii) about 20% of the system’s efficiency is decreased as the current density increases from 40 mA cm−2 to 200 mA cm−2; (iii) the optimal electrode thickness and electrode aspect ratio are 6 mm and 1:1, respectively; and (iv) reducing the compression ratio and increasing porosity are effective ways of lowering pump loss. Such in-depth analysis can not only provide a cost-effective method for optimizing and predicting the behaviors and performance of TIFBs but can also be of great benefit to the design, management, and manufacture of tin–iron flow batteries.
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Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Technologies Research · Membrane-based Ion Separation Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

Jiangsu Provincial Key Laboratory of Eco-Environmental Materials, Yancheng Institute of Technology, Yancheng 224051, China

Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150500, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Jiangsu Province · College Natural Science Research Project of Jiangsu Province · Open Project Program of Key Laboratory for Photonic and Electric Bandgap Materials, Ministry of Education

References (30)

Show source-provided references
1. Recent progress in zinc-based redox flow batteries: A review10.1088/1361-6463/ac4182 ↗
2. Analysis and optimization for multi-stack vanadium flow battery module incorporating electrode permeability10.1016/j.jpowsour.2021.230606 ↗
3. Perovskite enables high performance vanadium redox flow battery10.1016/j.cej.2022.136341 ↗
4. Carbon felt electrode modified by lotus seed shells for high-performance vanadium redox flow battery10.1016/j.cej.2022.138377 ↗
5. Near to neutral pH all-iron redox flow battery based on environmentally compatible coordination compounds10.1016/j.electacta.2022.141042 ↗
6. Low-cost all-iron flow battery with high performance towards long-duration energy storage10.1016/j.jechem.2022.06.041 ↗
7. Tuning the ferrous coordination structure enables a highly reversible Fe anode for long-life all-iron flow batteries10.1039/D1TA07295A ↗
8. Perspective of alkaline zinc-based flow batteries
9. Structural influence of the anode materials towards efficient Zn deposition/dissolution in aqueous Zn-Iodide flow batteries10.1149/1945-7111/abf4ee ↗
10. Review-Recent Advance in Self-Supported Electrocatalysts for Rechargeable Zinc-Air Batteries10.1149/1945-7111/aba96e ↗
11. Structural modification of negative electrode for Zinc—Nickel single-flow battery based on polarization analysis10.1149/1945-7111/ac0f5d ↗
12. Review of zinc dendrite formation in zinc bromine redox flow battery10.1016/j.rser.2020.109838 ↗
13. A facile preparation of λ-MnO2 as Cathode material for high-performance zinc-manganese redox flow battery10.1149/1945-7111/ab75c2 ↗
14. A two-dimensional transient model for a zinc-cerium redox flow battery validated by extensive experimental data10.1016/j.jpowsour.2021.230237 ↗
15. Zinc-Iron flow batteries with common electrolyte10.1149/2.0591706jes ↗
16. In Situ Defect-Free Vertically Aligned Layered Double Hydroxide Composite Membrane for High Areal Capacity and Long-Cycle Zinc-Based Flow Battery
17. Effect of a bromine complex agent on electrochemical performances of zinc electrodeposition and electrodissolution in Zinc—Bromide flow battery10.1016/j.jpowsour.2019.227020 ↗
18. Inhibition of zinc dendrites in zinc-based flow batteries10.3389/fchem.2020.00557 ↗
19. Xu, Z., and Wu, M. (2022). Toward Dendrite-Free Deposition in Zinc-Based Flow Batteries: Status and Prospects. Batteries, 8.10.3390/batteries8090117 ↗
20. A dendrite-free tin anode for high-energy aqueous redox flow batteries10.1002/adma.202008095 ↗
21. Study on a high current density redox flow battery with tin (II)/tin as negative couple10.1016/j.jpowsour.2015.01.049 ↗
22. A novel tin-bromine redox flow battery for large-scale energy storage10.1016/j.apenergy.2019.113756 ↗
23. A Sn-Fe flow battery with excellent rate and cycle performance10.1016/j.jpowsour.2018.10.011 ↗
24. Elucidating effects of component materials and flow fields on Sn-Fe hybrid flow battery10.1016/j.jpowsour.2019.227613 ↗
25. A low-cost neutral aqueous redox flow battery with dendrite-free tin Anode10.1149/1945-7111/ac39db ↗
26. Numerical investigation on the dispersion effect in vanadium redox flow battery10.1016/j.cej.2020.124753 ↗
27. Mathematical modeling and numerical analysis of alkaline zinc-iron flow batteries for energy storage applications10.1016/j.cej.2020.126684 ↗
28. Studies on pressure losses and flow rate optimization in vanadium redox flow battery10.1016/j.jpowsour.2013.09.071 ↗
29. A dynamic plug flow reactor model for a vanadium redox flow battery cell10.1016/j.jpowsour.2016.02.018 ↗
30. Mathematical modeling and in-depth analysis of 10 kW-class iron-vanadium flow batteries10.1016/j.jpowsour.2023.232813 ↗