journal article·2023-08-28

Boosting Charge Transfer of Fe Doping BiVO4/CoOx for Photoelectrochemical Water Splitting

Daoming Chen, Xiaolin Li, Jiayi Huang, Yuxuan Chen, Zili Liu, Yongchao Huang

ACS Applied Energy Materials· Volume 6· Issue 16
Publisher page

Abstract

Charge separation efficiency is the main obstacle to limiting the photoelectrochemical (PEC) water-splitting performance of bismuth vanadate (BiVO 4 ) photoanodes. Herein, we report a convenient and efficient strategy for Fe doping into BiVO 4 and hybrid CoO x OECs to obtain a Fe-BiVO 4 /CoO x photoanode. The resulting photoanode exhibits 4.0 mA/cm 2 photocurrent density as well as a high charge transfer (74.4%)/separation efficiency (71.2%) at 1.23 V vs reversible hydrogen electrode (RHE) under AM 1.5 G illumination. The synergistic effect of Fe doping and CoO x OEC loading can dramatically boost the electrical conductivity and carrier density of BiVO 4 . This work provides effective experimental data for improving the PEC performance of BiVO 4 .
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangdong Provincial Key Laboratory of Fuel Cell Technology, Guangzhou 510006, China

Funding

Natural Science Foundation of Guangzhou City · Guangzhou University · Guangdong Key Laboratory of Fuel Cell Technology · National Science Foundation of Guangdong Province · Yingde City

References (50)

Show source-provided references
1. 10.1016/j.apcatb.2023.12286510.1016/j.apcatb.2023.122865 ↗
2. 10.1021/jacs.1c0739110.1021/jacs.1c07391 ↗
3. 10.1016/j.apsusc.2022.15378610.1016/j.apsusc.2022.153786 ↗
4. 10.1039/C3CS60378D10.1039/C3CS60378D ↗
5. 10.1039/D0EE02397C10.1039/D0EE02397C ↗
6. 10.1016/j.mtsust.2022.10011810.1016/j.mtsust.2022.100118 ↗
7. 10.1016/j.cej.2020.12616310.1016/j.cej.2020.126163 ↗
8. 10.1021/acsaem.2c0077910.1021/acsaem.2c00779 ↗
9. 10.1002/anie.20191329510.1002/anie.201913295 ↗
10. 10.1002/smll.20210508410.1002/smll.202105084 ↗
11. 10.1002/aenm.20210238410.1002/aenm.202102384 ↗
12. 10.1038/s41560-021-00777-x10.1038/s41560-021-00777-x ↗
13. 10.1021/acsaem.1c0162310.1021/acsaem.1c01623 ↗
14. 10.1002/anie.20201090810.1002/anie.202010908 ↗
15. 10.1021/acsaem.2c0096310.1021/acsaem.2c00963 ↗
16. 10.1039/C6TA07177E10.1039/C6TA07177E ↗
17. 10.1002/anie.20191567110.1002/anie.201915671 ↗
18. 10.1021/acsaem.1c0362610.1021/acsaem.1c03626 ↗
19. 10.1021/acsenergylett.7b0021610.1021/acsenergylett.7b00216 ↗
20. 10.1002/cssc.20160076110.1002/cssc.201600761 ↗
21. 10.1038/s41560-023-01262-310.1038/s41560-023-01262-3 ↗
22. 10.1021/acs.energyfuels.2c0211910.1021/acs.energyfuels.2c02119 ↗
23. 10.1039/C7TA11132K10.1039/C7TA11132K ↗
24. 10.1002/adfm.20201121010.1002/adfm.202011210 ↗
25. 10.1039/C8TA09899A10.1039/C8TA09899A ↗
26. 10.1002/adfm.20227029010.1002/adfm.202270290 ↗
27. 10.1021/acscatal.1c0068610.1021/acscatal.1c00686 ↗
28. 10.1021/acscentsci.5b0040210.1021/acscentsci.5b00402 ↗
29. 10.1016/j.nanoen.2015.10.01810.1016/j.nanoen.2015.10.018 ↗
30. 10.1039/D1TA03786B10.1039/D1TA03786B ↗
31. 10.1021/acssuschemeng.1c0305510.1021/acssuschemeng.1c03055 ↗
32. 10.1038/nenergy.2016.19110.1038/nenergy.2016.191 ↗
33. 10.1039/D3CC00712J10.1039/D3CC00712J ↗
34. 10.1016/j.cej.2021.13102710.1016/j.cej.2021.131027 ↗
35. 10.1002/smll.20140050610.1002/smll.201400506 ↗
36. 10.1002/smll.20200160010.1002/smll.202001600 ↗
37. 10.1039/C6EE00036C10.1039/C6EE00036C ↗
38. 10.1016/j.jpowsour.2021.22996410.1016/j.jpowsour.2021.229964 ↗
39. 10.1038/ncomms976910.1038/ncomms9769 ↗
40. 10.1016/j.trac.2019.05.00210.1016/j.trac.2019.05.002 ↗
41. 10.1021/acsaem.1c0229110.1021/acsaem.1c02291 ↗
42. 10.1038/s41560-017-0057-010.1038/s41560-017-0057-0 ↗
43. 10.1039/D2SC06981D10.1039/D2SC06981D ↗
44. 10.1016/j.cej.2021.13009210.1016/j.cej.2021.130092 ↗
45. 10.1038/s41929-021-00724-910.1038/s41929-021-00724-9 ↗
46. 10.1016/j.coco.2022.10139010.1016/j.coco.2022.101390 ↗
47. 10.1002/anie.20110827610.1002/anie.201108276 ↗
48. 10.1002/smll.20220524610.1002/smll.202205246 ↗
49. 10.1039/C4TA04461D10.1039/C4TA04461D ↗
50. 10.1016/j.apcatb.2015.11.04310.1016/j.apcatb.2015.11.043 ↗