journal article·2023-03-13

Toward Ultralong Lifespan Aqueous Zinc-Ion Batteries via Sulfur-Defect Vanadium Tetrasulfide Cathode

Fangfang Wu, Yuxi Wang, Xiaojing Dai, Shibo Meng, Dong Zheng, Ruilian Yin, Wenxian Liu, Wenhui Shi, Xiehong Cao

ACS Applied Energy Materials· Volume 6· Issue 5
Publisher page

Abstract

Vanadium sulfide has become one of the promising cathodes of aqueous rechargeable zinc-ion batteries (AZIBs); however, the further application of vanadium sulfides for AZIBs is severely restricted by the limited specific capacity and poor cycling stability. Herein, we synthesize the vanadium tetrasulfide nanosphere with S-defects and coated by an ultrathin carbon layer (D-VS 4 ). The as-assembled Zn//D-VS 4 cell delivers a high specific capacity of 295 mAh g –1 at 0.5 A g –1 and long-time cycling stability (a capacity retention of 72.0% after 8,000 cycles). The electrochemical reaction mechanism of D-VS 4 is revealed. This work provides a significant supplement to the study of vanadium-based sulfides cathode for AZIBs.
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Research context

OpenAlex topics: Advanced battery technologies research · Perovskite Materials and Applications · Advanced Battery Materials and Technologies

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Affiliations

College of Materials Science and Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou 310014, Zhejiang, P. R. China

College of Chemical Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou 310014, Zhejiang, P. R. China

Center for Membrane Separation and Water Science & Technology, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou 310014, Zhejiang, P. R. China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Natural Science Foundation of Zhejiang Province · Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang

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