journal article·2022-09-26

In Situ K Doped γ-LiV2O5 as Long-Life Anode and Cathode for Lithium Ion Battery

Junfei Ma, Yu Chen, Yinyin Zhang, Ting Song, Xianyou Wang, Xiongwei Wu, Man-Kay Law, Bei Long

ACS Applied Energy Materials· Volume 5· Issue 9
Publisher page

Abstract

Based on the reaction process (γ′-V2O5 ↔ γ-LiV2O5 ↔ ζ-Li2V2O5 ↔ ω-Li3V2O5), γ-LiV2O5 is potential anode and cathode in a lithium ion battery. However, its poor structural stability during lithiation/delithiation results in unsatisfactory cyclic life. This work reports a low-temperature molten salt method to prepare in situ K doped γ-LiV2O5. With the as-prepared electrode acting as both anode (233 mAh g–1 after 2400 cycles at 1 A g–1) and cathode (128 mAh g–1 after 888 cycles at 0.2 A g–1), experimental results reveal that the K+ doping distinctly improves structural reversibility, demonstrating the superior electrochemical properties of γ-LiV2O5 for becoming an outstanding candidate in lithium ion batteries.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Transition Metal Oxide Nanomaterials · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry, Xiangtan University, Xiangtan 411105, China

School College of Electrical and Information Engineering, Hunan University, Changsha 410082, China

State Key Laboratory of Analog and Mixed-Signal VLSI, University of Macau, Macau 999078, China

Funding

Natural Science Foundation of?Hunan Province · China Postdoctoral Science Foundation · National Natural Science Foundation of China · Jiangsu Donghua Analysis Instruments Co. Ltd. · Macao Young Scholars Program

References (30)

Show source-provided references
1. 10.1016/j.cej.2018.10.22310.1016/j.cej.2018.10.223 ↗
2. 10.1002/adma.20190620510.1002/adma.201906205 ↗
3. 10.1021/acsami.6b0130510.1021/acsami.6b01305 ↗
4. 10.20517/energymater.2021.2110.20517/energymater.2021.21 ↗
5. 10.1002/adma.20170157110.1002/adma.201701571 ↗
6. 10.1007/s12274-020-3118-910.1007/s12274-020-3118-9 ↗
7. 10.1007/s12598-021-01944-510.1007/s12598-021-01944-5 ↗
8. 10.1016/j.cej.2019.03.16710.1016/j.cej.2019.03.167 ↗
9. 10.1002/smll.20160314810.1002/smll.201603148 ↗
10. 10.1007/s11426-020-9845-510.1007/s11426-020-9845-5 ↗
11. 10.1016/j.jallcom.2022.16535410.1016/j.jallcom.2022.165354 ↗
12. 10.1063/1674-0068/26/05/597-60010.1063/1674-0068/26/05/597-600 ↗
13. 10.1039/C4TA00090K10.1039/C4TA00090K ↗
14. 10.1006/jssc.1999.831410.1006/jssc.1999.8314 ↗
15. 10.1021/acs.jpcc.5b0554010.1021/acs.jpcc.5b05540 ↗
16. 10.1016/j.apsusc.2021.15149010.1016/j.apsusc.2021.151490 ↗
17. 10.1002/smtd.20190018710.1002/smtd.201900187 ↗
18. 10.1016/S0167-2738(97)00112-410.1016/S0167-2738(97)00112-4 ↗
19. 10.1016/j.apsusc.2019.05.19610.1016/j.apsusc.2019.05.196 ↗
20. 10.1007/s11434-015-0970-110.1007/s11434-015-0970-1 ↗
21. 10.1016/j.jcis.2021.10.11310.1016/j.jcis.2021.10.113 ↗
22. 10.1016/j.nanoen.2019.01.08010.1016/j.nanoen.2019.01.080 ↗
23. 10.1016/j.jcis.2021.07.14110.1016/j.jcis.2021.07.141 ↗
24. 10.1016/j.electacta.2022.14016110.1016/j.electacta.2022.140161 ↗
25. 10.1016/j.ssi.2003.09.01110.1016/j.ssi.2003.09.011 ↗
26. 10.1007/s10008-012-1659-x10.1007/s10008-012-1659-x ↗
27. 10.1016/j.ensm.2022.06.04210.1016/j.ensm.2022.06.042 ↗
28. 10.1016/j.ensm.2022.05.01910.1016/j.ensm.2022.05.019 ↗
29. 10.1021/acsaem.1c0039610.1021/acsaem.1c00396 ↗
30. 10.1021/acs.nanolett.6b0094210.1021/acs.nanolett.6b00942 ↗