All-Solid-State Batteries with LiCoO2-Type Electrodes: Realization of an Impurity-Free Interface by Utilizing a Cosinterable Li3.5Ge0.5V0.5O4 Electrolyte
Source abstract
Abstract
An impurity-free interface was achieved in an oxide-based all-solid-state battery (ASSB) after cosintering, which was facilitated by an enhanced thermal stability between the layered rock-salt LiMO2 electrode materials (LiCoO2 or LiNi1/3Mn1/3Co1/3O2 (NMC)) and a lithium superionic conductor (LISICON)-type Li3.5Ge0.5V0.5O4 (LGVO) electrolyte. The ionic conductivity of LGVO reached 9.6 × 10–5 S cm–1, which is the highest reported conductivity for an LISICON oxide. These characteristics facilitated a good reversible capacity in the NMC electrode in an ASSB fabricated via cosintering. The high interfacial thermal stability between LiMO2 and LISICON is a useful property in the context of oxide-based ASSBs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan
Funding
Advanced Low Carbon Technology Research and Development Program
References (26)
Show source-provided references
1. 10.1021/acs.chemrev.9b0026810.1021/acs.chemrev.9b00268 ↗
2. 10.1002/aenm.20190181010.1002/aenm.201901810 ↗
3. 10.1021/acs.chemmater.8b0171310.1021/acs.chemmater.8b01713 ↗
4. 10.1021/acs.chemmater.6b0387010.1021/acs.chemmater.6b03870 ↗
5. 10.1021/acsami.6b0905910.1021/acsami.6b09059 ↗
6. 10.1007/s11581-017-2276-610.1007/s11581-017-2276-6 ↗
7. 10.1021/acs.chemmater.8b0174610.1021/acs.chemmater.8b01746 ↗
8. 10.1016/j.jpowsour.2013.02.07310.1016/j.jpowsour.2013.02.073 ↗
9. 10.1016/j.ssi.2016.01.04510.1016/j.ssi.2016.01.045 ↗
10. 10.1016/j.ssi.2018.09.01110.1016/j.ssi.2018.09.011 ↗
11. 10.1021/acsaem.9b0126810.1021/acsaem.9b01268 ↗
12. 10.1002/adfm.20110247910.1002/adfm.201102479 ↗
13. 10.1134/S002016852002008910.1134/S0020168520020089 ↗
14. 10.1016/0025-5408(80)90012-410.1016/0025-5408(80)90012-4 ↗
15. 10.1016/0013-4686(78)80023-110.1016/0013-4686(78)80023-1 ↗
16. 10.1016/0022-4596(82)90383-810.1016/0022-4596(82)90383-8 ↗
17. 10.1016/0167-2738(80)90003-X10.1016/0167-2738(80)90003-X ↗
18. 10.1016/0025-5408(80)90249-410.1016/0025-5408(80)90249-4 ↗
19. 10.1021/acsaem.9b0115210.1021/acsaem.9b01152 ↗
20. 10.1016/0167-2738(85)90002-510.1016/0167-2738(85)90002-5 ↗
21. 10.4028/www.scientific.net/SSP.130.1510.4028/www.scientific.net/SSP.130.15 ↗
22. 10.1021/acsaem.8b0127810.1021/acsaem.8b01278 ↗
23. 10.1021/acsaem.9b0194910.1021/acsaem.9b01949 ↗
24. 10.1016/j.jpowsour.2016.03.05910.1016/j.jpowsour.2016.03.059 ↗
25. 10.1016/0167-2738(89)90058-110.1016/0167-2738(89)90058-1 ↗
26. 10.1111/j.1551-2916.2008.02503.x10.1111/j.1551-2916.2008.02503.x ↗