journal article·2020-07-27

Sulfur-Rich Molybdenum Sulfide as a Cathode Material for Room Temperature Sodium–Sulfur Batteries

Melissa L. Meyerson, Philippe E. Papa, Jason A. Weeks, Austin G. Paul-Orecchio, Adam Heller, C. Buddie Mullins

ACS Applied Energy Materials· Volume 3· Issue 7
Publisher page

Abstract

The low cost, abundance, and high capacity of sodium and sulfur make them attractive battery materials. However, formation and migration of polysulfides in sulfur batteries causes rapid capacity fade, limiting battery cycle life. Most strategies to mitigate polysulfide shuttling address migration rather than formation and require complicated or expensive synthetic steps. Here, we introduce an amorphous, sulfur-rich molybdenum sulfide as a sulfur equivalent cathode that is simple and easy to make and shows excellent cycling performance with a specific capacity of 537 mAh g–1 at 50 mA g–1, retaining over 200 mAh g–1 at a rate of 1 A g–1.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States

McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712-0231, United States

Center for Electrochemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States

Texas Materials Institute, University of Texas at Austin, Austin, Texas 78712-0231, United States

Funding

Welch Foundation · Division of Chemical, Bioengineering, Environmental, and Transport Systems

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