journal article·2022-01-24

Functional Ligand-Decorated ZnO Nanoparticles as Cathode Interlayers for Efficient Organic Solar Cells

Xing Chen, Zhou Zhang, Chaowei Zhao, Jie Fang, Dongdong Xia, Yuefeng Zhang, Chengyi Xiao, Yonggang Wu, Shengyong You, Weiwei Li

ACS Applied Energy Materials· Volume 5· Issue 1
Publisher page

Abstract

ZnO as an interlayer plays an important role in organic solar cells (OSCs). There are two kinds of ZnO interlayers, including sol–gel method-obtained interlayers and those obtained using ZnO nanocrystals. While sol–gel ZnO interlayers require thermal treatment, ZnO nanocrystals can generate thin film interlayers without extra treatment. However, ZnO nanocrystals in solution are usually unstable due to strong aggregation, limiting their long-term application. In this work, we reported a method to stabilize ZnO nanocrystals by using a ligand of dimethylglycine. The resulting ZnO–N nanocrystals exhibit high stability in solution, as well as aligned energy levels and efficient charge extraction properties. The application of ZnO–N nanocrystals into OSCs provided a high efficiency of ∼17%, while unmodified ZnO-based solar cells showed a low efficiency of 14.2%.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Perovskite Materials and Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330096, China

College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China

Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Funding

Ministry of Science and Technology of the People's Republic of China · Jiangxi Provincial Department of Science and Technology · National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities · Jiangxi Academy of Sciences · Open Project of State Key Laboratory of Supramolecular Structure and Materials

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