journal article·2021-10-25

Conjugated Ladder-Type Polymer with Hexaazatriphenylene Units as a Cathode Material for Lithium, Sodium, and Potassium Batteries

Roman R. Kapaev, Alexander F. Shestakov, Sergey G. Vasil’ev, Keith J. Stevenson

ACS Applied Energy Materials· Volume 4· Issue 10
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Abstract

A ladder-type conjugated polymer with hexaazatriphenylene moieties is reported, and its application as a cathode material for Li-, Na-, and K-based batteries is assessed. The material demonstrates specific capacities of 170–180 mA h g–1 at 0.1 A g–1, and up to 113 mA h g–1 at 5 A g–1 (charge/discharge in ∼80 s). It also shows superior cycling stability, especially in potassium cells that show no capacity fade after 4000 cycles at 5 A g–1. Charge–discharge processes of the material are probed using operando Raman spectroscopy.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow 121205, Russia

Institute of Problems of Chemical Physics RAS, Acad. Semenov Av. 1, Chernogolovka 142432, Russia

Funding

Russian Foundation for Basic Research

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