Efficient Near-Infrared Light-Driven Hydrogen Evolution Catalyzed by a Saddle-Distorted Porphyrin as a Photocatalyst
Source abstract
Abstract
Development of a near-infrared (NIR) light-induced hydrogen (H2) evolution system is indispensable for constructing a sustainable society wherein the utilization of solar energy is maximized. Here, we report NIR light-driven H2 evolution catalyzed by a combination of a diprotonated saddle-distorted porphyrin as a photosensitizer and platinum nanoparticles as a H2-evolving catalyst. The quantum yield at 710 nm was determined to be 17%, which is the highest value among photocatalytic H2-evolution systems ever reported.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metalloenzymes and iron-sulfur proteins · Advanced Nanomaterials in Catalysis · Nanocluster Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan
Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama 223-8522, Japan
Funding
Core Research for Evolutional Science and Technology · Japan Society for the Promotion of Science
References (34)
Show source-provided references
1. Pogutz S. · 200910.4337/9781848449329 ↗
2. 10.1002/cssc.20100018210.1002/cssc.201000182 ↗
3. 10.1021/cr050193e10.1021/cr050193e ↗
4. 10.1039/c1cc12390d10.1039/c1cc12390d ↗
5. 10.1021/ar900253e10.1021/ar900253e ↗
6. 10.1021/ar500160510.1021/ar5001605 ↗
7. 10.1016/j.ccr.2017.07.01410.1016/j.ccr.2017.07.014 ↗
8. 10.1021/acs.accounts.5b0005810.1021/acs.accounts.5b00058 ↗
9. 10.1021/ja303698e10.1021/ja303698e ↗
10. 10.1021/jacs.6b1297610.1021/jacs.6b12976 ↗
11. 10.1002/anie.20161231510.1002/anie.201612315 ↗
12. 10.1021/jacs.8b1154410.1021/jacs.8b11544 ↗
13. 10.1039/C5CC02124C10.1039/C5CC02124C ↗
14. 10.1002/anie.20170899610.1002/anie.201708996 ↗
15. 10.1039/C8CC03631D10.1039/C8CC03631D ↗
16. 10.1038/s41557-019-0397-410.1038/s41557-019-0397-4 ↗
17. Dolphin D. · 1978 · 3
18. 10.1016/j.ccr.2014.10.00110.1016/j.ccr.2014.10.001 ↗
19. 10.1021/jp400381h10.1021/jp400381h ↗
20. 10.1016/S0040-4020(98)00015-510.1016/S0040-4020(98)00015-5 ↗
21. 10.1021/ja961227q10.1021/ja961227q ↗
22. 10.1039/c0pp00107d10.1039/c0pp00107d ↗
23. 10.1021/ja00051a01910.1021/ja00051a019 ↗
24. 10.1039/C8GC00295A10.1039/C8GC00295A ↗
25. 10.1039/C9CC01547G10.1039/C9CC01547G ↗
26. 10.1021/ja806261q10.1021/ja806261q ↗
27. 10.1016/j.ccr.2012.01.01110.1016/j.ccr.2012.01.011 ↗
28. 10.1002/anie.20180628110.1002/anie.201806281 ↗
29. 10.1021/jacs.9b0103810.1021/jacs.9b01038 ↗
30. 10.1021/nl401568x10.1021/nl401568x ↗
31. 10.1002/chem.20100239910.1002/chem.201002399 ↗
32. 10.1021/jacs.8b1336610.1021/jacs.8b13366 ↗
33. 10.1039/C7CC03635C10.1039/C7CC03635C ↗
34. 10.1021/ja00073a01010.1021/ja00073a010 ↗