journal article·2023-09-25Open access

AgBTC MOF-Mediated Approach to Synthesize Silver Nanoparticles Decorated on Reduced Graphene Oxide (rGO@Ag) for Energy Storage Applications

Arturo Barjola, Anastasia Rapeyko, Oscar Sahuquillo, Francesc X. Llabrés i Xamena, Enrique Giménez

ACS Applied Energy Materials· Volume 6· Issue 18

Abstract

High Resolution Image Download MS PowerPoint Slide Nanowires of silver-based metal–organic framework (MOF) (AgBTC, BTC = 1,3,5-benzenetricarboxylate) were grown onto graphene oxide layers to generate GO-AgBTC nanocomposites. Thermal treatment of these composites in inert atmosphere produced reduced graphene oxide (rGO) decorated with well-dispersed and homogeneous silver nanoparticles ( [email protected] ). The easy and scalable synthesis of AgNPs via MOF-mediated synthesis was achieved by the thermal decomposition of the AgBTC directly onto the rGO surface. The structure, morphology, and electrochemical properties of this novel material were investigated by XRD, Raman, TGA, FE-SEM, TEM, cyclic voltammetry, and galvanostatic charge and discharge experimental techniques. The results showed improved capacitive features for [email protected] Specific gravimetric capacitance measured by galvanostatic charge–discharge yielded a value of 151.97 F/g at the current density of 0.5 A/g, pointing out that MOF-mediated synthesis offers a facile method to generate rGO electrodes decorated by uniformly distributed nanoparticles for energy storage devices.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Instituto de Tecnología de Materiales, Universitat Politècnica de València (UPV), Camino de Vera s/n, 46022 Valencia, Spain

Instituto de Tecnología Química, Universitat Politècnica de València−Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos, s/n, Valencia 46022, Spain

Funding

Agencia Estatal de Investigaci?n

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