journal article·2022-11-03Open access

The Gel-State Electrolytes in Zinc-Ion Batteries

Fulong Hu, Maoyun Li, Guowei Gao, Huiqing Fan, Longtao Ma

Batteries· Volume 8· Issue 11

Abstract

Zinc-ion batteries (ZIBs) are receiving increasing research attention due to their high energy density, resource abundance, low-cost, intrinsic high-safety properties, and the appropriate plating/stripping voltage. Gel-state electrolytes possess merits of having a wide electrochemical window, good flexibility, superior water retainability, and excellent compatibility with aqueous electrolytes, which makes them potential candidates for flexible batteries. However, the practical applications of ZIBs with gel-state electrolytes still have some issues of water content easily dropping, poor mechanical stability, and the interface problem. Therefore, the application of hydrogel-based, self-healing gel, gel polymer, thermos-reversible, and other additional functions of gel electrolytes in ZIBs are discussed in this review. Following that, the design of multi-functional gel-state electrolytes for ZIBs is proposed. Finally, the prospect and the challenges of this type of battery are described.
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Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Frontiers Science Center for Flexible Electronics, Institute of Flexible Electronics, Northwestern Polytechnical University, Xi’an 710072, China

State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China

Funding

Fundamental Research Funds for the Central Universities

References (65)

Show source-provided references
1. Recent Status and Future Perspectives of Ultracompact and Customizable Micro-Supercapacitors10.26599/NRE.2022.9120018 ↗
2. High-Energy-Density Magnesium-Air Battery Based on Dual-Layer Gel Electrolyte10.1002/anie.202104536 ↗
3. Permselective Metal-Organic Framework Gel Membrane Enables Long-Life Cycling of Rechargeable Organic Batteries10.1038/s41565-020-00788-x ↗
4. Tuning the Interlayer Spacing of Graphene Laminate Films for Efficient Pore Utilization Towards Compact Capacitive Energy Storage10.1038/s41560-020-0560-6 ↗
5. Metal-Tellurium Batteries: A Rising Energy Storage System10.1002/sstr.202000005 ↗
6. Building Aqueous K-Ion Batteries for Energy Storage10.1038/s41560-019-0388-0 ↗
7. Robust Lithium–Sulfur Batteries Enabled by Highly Conductive Wse2-Based Superlattices with Tunable Interlayer Space10.1002/adfm.202201322 ↗
8. A Flexible Electron-Blocking Interfacial Shield for Dendrite-Free Solid Lithium Metal Batteries10.1038/s41467-020-20463-y ↗
9. Sustainable Lithium-Metal Battery Achieved by a Safe Electrolyte Based on Recyclable and Low-Cost Molecular Sieve10.1002/anie.202104124 ↗
10. Selectively Wetted Rigid–Flexible Coupling Polymer Electrolyte Enabling Superior Stability and Compatibility of High-Voltage Lithium Metal Batteries10.1002/aenm.201903939 ↗
11. Long-Cycling and Safe Lithium Metal Batteries Enabled by the Synergetic Strategy of Ex Situ Anodic Pretreatment and an in-Built Gel Polymer Electrolyte10.1039/D0TA02148B ↗
12. Asymmetric Gel Polymer Electrolyte with High Lithium Ion Conductivity for Dendrite-Free Lithium Metal Batteries10.1039/D0TA01883J ↗
13. Li Metal Deposition and Stripping in a Solid-State Battery Via Coble Creep10.1038/s41586-020-1972-y ↗
14. Self-Assembling Films of Covalent Organic Frameworks Enable Long-Term, Efficient Cycling of Zinc-Ion Batteries10.1002/adma.202101726 ↗
15. Asymmetric Polymer Electrolyte Constructed by Metal–Organic Framework for Solid-State, Dendrite-Free Lithium Metal Battery10.1002/adfm.202007198 ↗
16. Robust and Flexible Polymer/Mxene-Derived Two Dimensional Tio2 Hybrid Gel Electrolyte for Dendrite-Free Solid-State Zinc-Ion Batteries10.1016/j.cej.2021.132748 ↗
17. High Voltage and Self-Healing Zwitterionic Double-Network Hydrogels as Electrolyte for Zinc-Ion Hybrid Supercapacitor/Battery10.1016/j.ijhydene.2022.05.195 ↗
18. Ultra-Long-Life and Highly Reversible Zn Metal Anodes Enabled by a Desolvation and Deanionization Interface Layer10.1039/D0EE03898A ↗
19. Reducing Water Activity by Zeolite Molecular Sieve Membrane for Long-Life Rechargeable Zinc Battery10.1002/adma.202102415 ↗
20. Hydrophobic Organic-Electrolyte-Protected Zinc Anodes for Aqueous Zinc Batteries10.1002/anie.202008634 ↗
21. A Liquid Metal Assisted Dendrite-Free Anode for High-Performance Zn-Ion Batteries10.1039/D0TA11828A ↗
22. Liu, C., Lu, Q., Omar, A., and Mikhailova, D. (2021). A Facile Chemical Method Enabling Uniform Zn Deposition for Improved Aqueous Zn-Ion Batteries. Nanomaterials, 11.10.3390/nano11030764 ↗
23. A Metal-Organic Framework as a Multifunctional Ionic Sieve Membrane for Long-Life Aqueous Zinc-Iodide Batteries10.1002/adma.202004240 ↗
24. Zwitterionic Sulfobetaine Hydrogel Electrolyte Building Separated Positive/Negative Ion Migration Channels for Aqueous Zn-Mno2 Batteries with Superior Rate Capabilities10.1002/aenm.202000035 ↗
25. Symmetric Is Nonidentical: Operation History Matters for Zn Metal Anode10.26599/NRE.2022.9120023 ↗
26. Fundamentals and Perspectives of Electrolyte Additives for Aqueous Zinc-Ion Batteries10.1016/j.ensm.2020.10.019 ↗
27. Ultrafast Zinc–Ion–Conductor Interface toward High-Rate and Stable Zinc Metal Batteries10.1002/aenm.202100186 ↗
28. Recent Advances of Composite Solid-State Electrolytes for Lithium-Based Batteries10.1021/acs.energyfuels.1c01609 ↗
29. Liquid-Free All-Solid-State Zinc Batteries and Encapsulation-Free Flexible Batteries Enabled by in Situ Constructed Polymer Electrolyte10.1002/anie.202011788 ↗
30. Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry10.1021/acs.chemrev.9b00628 ↗
31. Self-Healing Solid Polymer Electrolyte with High Ion Conductivity and Super Stretchability for All-Solid Zinc-Ion Batteries10.1021/acsami.1c09200 ↗
32. Advanced Polymer-Based Electrolytes in Zinc–Air Batteries10.1016/j.esci.2022.08.004 ↗
33. Progress and Perspective of Ceramic/Polymer Composite Solid Electrolytes for Lithium Batteries10.1002/advs.201903088 ↗
34. Recent Progress and Perspectives on Aqueous Zn-Based Rechargeable Batteries with Mild Aqueous Electrolytes10.1016/j.ensm.2019.04.022 ↗
35. A Nanofibrillated Cellulose/Polyacrylamide Electrolyte-Based Flexible and Sewable High-Performance Zn-MnO2 Battery with Superior Shear Resistance10.1002/smll.201803978 ↗
36. Electrocatalytic Iodine Reduction Reaction Enabled by Aqueous Zinc-Iodine Battery with Improved Power and Energy Densities10.1002/anie.202014447 ↗
37. Velez, A.A.I., Reyes, E., Diaz Barrios, A., Santos, F., Fernandez Romero, A.J., and Tafur, J.P. (2021). Properties of the Pva-Vavtd Koh Blend as a Gel Polymer Electrolyte for Zinc Batteries. Gels, 7.10.3390/gels7040256 ↗
38. Polyacrylic Acid Assisted Synthesis of Free-Standing Mno2/CNTs Cathode for Zinc-Ion Batteries10.1088/1361-6528/ab9866 ↗
39. Effective Influences of 1-Ethyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl) Imide (Emimtfsi) Ionic Liquid on the Ion Transport Properties of Micro-Porous Zinc-Ion Conducting Poly (Vinyl Chloride) /Poly (Ethyl Methacrylate) Blend-Based Polymer Electrolytes10.1007/s10965-016-1043-0 ↗
40. Flexible, Hybrid Nanogenerator Based on Zinc Ferrite Nanorods Incorporated Poly(Vinylidene Fluoride-Co-Hexafluoropropylene) Nanocomposite for Versatile Mechanical Energy Harvesting10.1016/j.materresbull.2019.110515 ↗
41. Reaction and Thermal Behavior of Vitrimer-Like Polyhydroxy Esters Based on Polyethylene Glycol Diglycidyl Ether10.1002/app.49329 ↗
42. Raft Synthesis of Polystyrene-Block-Poly(Polyethylene Glycol Monomethyl Ether Acrylate) for Zinc Phthalocyanine-Loaded Polymeric Micelles as Photodynamic Therapy Photosensitizers. J. Polym10.1002/pola.28929 ↗
43. Flexible, Fiber-Shaped, Quasi-Solid-State Zn-Polyaniline Batteries with Methanesulfonic Acid-Doped Aqueous Gel Electrolyte10.1016/j.ensm.2020.12.009 ↗
44. Fundamental Study on Zn Corrosion and Dendrite Growth in Gel Electrolyte Towards Advanced Wearable Zn-Ion Battery10.1016/j.cej.2022.137021 ↗
45. Steric Molecular Combing Effect Enables Ultrafast Self-Healing Electrolyte in Quasi-Solid-State Zinc-Ion Batteries10.1021/acsenergylett.2c01459 ↗
46. Towards Dynamic but Supertough Healable Polymers through Biomimetic Hierarchical Hydrogen-Bonding Interactions10.1002/anie.201807622 ↗
47. A Self-Healing Flexible Quasi-Solid Zinc-Ion Battery Using All-in-One Electrodes10.1002/advs.202004689 ↗
48. Transparent, Highly Stretchable, Rehealable, Sensing, and Fully Recyclable Ionic Conductors Fabricated by One-Step Polymerization Based on a Small Biological Molecule10.1002/adfm.201902467 ↗
49. High Electrochemical and Mechanical Performance of Zinc Conducting-Based Gel Polymer Electrolytes10.1038/s41598-021-92671-5 ↗
50. Potassium Polyacrylate-Based Gel Polymer Electrolyte for Practical Zn-Ni Batteries10.1021/acsami.1c20999 ↗
51. Near-Neutral Flexible Zinc-Air Batteries with High Power Densities and Long Cycle Life Using Chloride-Based Gel Polymer Electrolytes10.1016/j.elecom.2022.107240 ↗
52. Flexible Wide-Temperature Zinc-Ion Battery Enabled by an Ethylene Glycol-Based Organohydrogel Electrolyte10.1021/acsaem.1c02433 ↗
53. Thermoreversible Polymer Gel Electrolytes10.1016/0032-3861(94)90896-6 ↗
54. A Smart Flexible Zinc Battery with Cooling Recovery Ability10.1002/anie.201704373 ↗
55. A Smart Safe Rechargeable Zinc Ion Battery Based on Sol-Gel Transition Electrolytes10.1016/j.scib.2018.06.019 ↗
56. High-Performance Anti-Freezing Flexible Zn-Mno2 Battery Based on Polyacrylamide/Graphene Oxide/Ethylene Glycol Gel Electrolyte10.3389/fchem.2020.00603 ↗
57. Quasi-Solid-State Zinc Ion Rechargeable Batteries for Subzero Temperature Applications10.1021/acsaem.0c01452 ↗
58. Anti-Freezing Flexible Aqueous Zn–Mno2 Batteries Working at −35 °C Enabled by a Borax-Crosslinked Polyvinyl Alcohol/Glycerol Gel Electrolyte10.1039/D0TA01553A ↗
59. A Flexible Rechargeable Aqueous Zinc Manganese-Dioxide Battery Working at −20 °C10.1039/C8EE02892C ↗
60. Supramolecular Hydrophobic Aggregates in Hydrogels Partially Inhibit Ice Formation10.1021/acs.jpcb.6b02863 ↗
61. CO2-Sourced Anti-Freezing Hydrogel Electrolyte for Sustainable Zn-Ion Batteries10.1016/j.cej.2022.135051 ↗
62. Flexible and Anti-Freezing Zinc-Ion Batteries Using a Guar-Gum/Sodium-Alginate/Ethylene-Glycol Hydrogel Electrolyte10.1016/j.ensm.2021.06.034 ↗
63. Porous Nanocomposite Gel Polymer Electrolyte with High Ionic Conductivity and Superior Electrolyte Retention Capability for Long-Cycle-Life Flexible Zinc–Air Batteries10.1016/j.nanoen.2018.11.057 ↗
64. Thermal-Switching and Repeatable Self-Protective Hydrogel Polyelectrolytes for Energy Storage Applications of Flexible Electronics10.1021/acsaem.1c00922 ↗
65. A Rechargeable Aqueous Zn2+-Battery with High Power Density and a Long Cycle-Life10.1039/C8EE01883A ↗