DataVXACS Applied Energy MaterialsPaper
journal article·2021-09-27Open access

Robust, Transparent Hybrid Thin Films of Phase-Change Material Sb2S3 Prepared by Electrophoretic Deposition

Christopher L. Hassam, Flavien Sciortino, Ngan T.K. Nguyen, Bhuvanesh Srinivasan, Katsuhiko Ariga, Franck Gascoin, Fabien Grasset, Takao Mori, Tetsuo Uchikoshi, Yohann Thimont, David Berthebaud

ACS Applied Energy Materials· Volume 4· Issue 9
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Source abstract

Abstract

Thin films of polyethylenimine-stabilized Sb2S3 are prepared via electrophoretic deposition (EPD), showing strong adhesion between the deposited layers and the underlying substrate, with the films being crystallized via annealing. For amorphous films, thicknesses can be freely tuned from 0.2 to 1 μm, shrinking to 0.1–0.5 μm when crystallized, while retaining a crack- and defect-free surface, thus not impacting their good stability and maintaining their optical properties. Through UV–vis spectroscopy and subsequent modeling of the obtained spectra, it was concluded that the materials after annealing showed a reduced band gap and a demonstrably increased refractive index (n) and carrier concentration. The use of EPD for this material shows the viability of rapidly creating stable thin films of phase-change materials.
Source: openalex_inverted_index · Quality: baseline

Research context

Materials processing

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Phase-change materials and chalcogenides · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CNRS-Saint Gobain-NIMS, IRL 3629, Laboratory for Innovative Key Materials and Structures (LINK), National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan

Laboratoire CRISMAT UMR 6508 CNRS ENSICAEN UCBN, 6 Boulevard du Maréchal Juin, 14050 CEDEX 04 Caen, France

WPI International Center for Materials Nanoarchitechtonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba 305-0044, Japan

National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

Univ. Rennes − CNRS − Institut des Sciences Chimiques de Rennes, UMR 6226, 35000 Rennes, France

Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8671, Japan

CIRIMAT, Université de Toulouse, CNRS, Université Toulouse 3 - Paul Sabatier, 118 Route de Narbonne, 31062 CEDEX 9 Toulouse, France

Funding

Japan Society for the Promotion of Science · Japan Science and Technology Agency · Centre National de la Recherche Scientifique

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