Electrochemical Production of 2,5-Furandicarboxylic from 5-Hydroxymethylfurfural Using Ultrathin Co(OH)2 on ZIF-67
Source abstract
Abstract
Electro-oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-furandicarboxylic acid (FDCA) requires a high applied potential to achieve a high FDCA yield. In this work, ultrathin Co(OH)2 on the ZIF-67 metal–organic framework has been designed as an efficient electrocatalyst for a high FDCA yield at a low applied potential. The obtained Co(OH)2@ZIF-67 electrocatalyst provides excellent catalytic performance with a 90.9% conversion, a 81.8% yield of FDCA, and 83.6% of faradaic efficiency. Importantly, the applied potential of the reaction has been reduced to 1.42 V (vs RHE), which is one of the lowest potentials among electrocatalysts developed for this reaction. The reaction mechanism has been proposed based on high-performance liquid chromatography analysis and DFT calculations, which reveal the importance of the 5-HMF binding mode on product selectivity. The synergistic effect from the Co(OH)2 active surface and ZIF-67 porous support on the high catalytic efficiency has been investigated by electrochemical surface area and pore characteristic analysis to provide a better understanding on the catalyst.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Catalysis for Biomass Conversion · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand
Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand
School of Bio-Chemical Engineering and Technology, Sirindhorn International Institute of Technology, Thammasat University, Pathumthani 12120, Thailand
School of Information Science and Technology, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand
Research Network of NANOTEC-VISTEC on Nanotechnology for Energy, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand
Funding
National Nanotechnology Center · Ministry of Higher Education, Science, Research and Innovation, Thailand
References (62)
Show source-provided references
1. 10.1039/c5py00686d10.1039/c5py00686d ↗
2. 10.1016/j.eurpolymj.2016.08.00410.1016/j.eurpolymj.2016.08.004 ↗
3. 10.1021/acs.oprd.7b0022310.1021/acs.oprd.7b00223 ↗
4. 10.1016/j.apcata.2017.09.01210.1016/j.apcata.2017.09.012 ↗
5. 10.1039/C7RA05427K10.1039/C7RA05427K ↗
6. 10.1039/C2RA21811A10.1039/C2RA21811A ↗
7. 10.1016/j.cattod.2010.06.00410.1016/j.cattod.2010.06.004 ↗
8. 10.1021/acscatal.5b0149110.1021/acscatal.5b01491 ↗
9. 10.1039/C8GC02680G10.1039/C8GC02680G ↗
10. 10.1016/j.cattod.2012.05.00810.1016/j.cattod.2012.05.008 ↗
11. 10.1039/C8CY00533H10.1039/C8CY00533H ↗
12. 10.1021/acscatal.7b0315210.1021/acscatal.7b03152 ↗
13. 10.1002/adma.20200045510.1002/adma.202000455 ↗
14. 10.1002/cssc.20180053210.1002/cssc.201800532 ↗
15. 10.1021/acscatal.8b0400310.1021/acscatal.8b04003 ↗
16. 10.1016/0013-4686(91)85084-K10.1016/0013-4686(91)85084-K ↗
17. 10.1021/acscatal.8b0101710.1021/acscatal.8b01017 ↗
18. 10.1039/C9GC02880C10.1039/C9GC02880C ↗
19. 10.1039/C8CS00268A10.1039/C8CS00268A ↗
20. 10.1039/D0CC02206C10.1039/D0CC02206C ↗
21. 10.1021/acssuschemeng.9b0020310.1021/acssuschemeng.9b00203 ↗
22. 10.1021/jacs.6b0712710.1021/jacs.6b07127 ↗
23. 10.1002/anie.20160379810.1002/anie.201603798 ↗
24. 10.1021/acsenergylett.7b0067910.1021/acsenergylett.7b00679 ↗
25. 10.1021/acsenergylett.6b0014410.1021/acsenergylett.6b00144 ↗
26. 10.1039/C5EE01155H10.1039/C5EE01155H ↗
27. 10.1002/adfm.20170416910.1002/adfm.201704169 ↗
28. 10.1002/anie.20180892910.1002/anie.201808929 ↗
29. 10.1002/anie.20030061010.1002/anie.200300610 ↗
30. 10.1039/C5EE00762C10.1039/C5EE00762C ↗
31. 10.1039/C9TA02169H10.1039/C9TA02169H ↗
32. 10.1038/ncomms1094210.1038/ncomms10942 ↗
33. 10.1038/s41467-019-13051-210.1038/s41467-019-13051-2 ↗
34. 10.1073/pnas.060243910310.1073/pnas.0602439103 ↗
35. 10.1039/C7TA08268A10.1039/C7TA08268A ↗
36. 10.1021/ar900116g10.1021/ar900116g ↗
37. 10.1126/science.115251610.1126/science.1152516 ↗
38. 10.1002/anie.20150424210.1002/anie.201504242 ↗
39. 10.1039/C6CC03149H10.1039/C6CC03149H ↗
40. 10.1021/jacs.6b0504610.1021/jacs.6b05046 ↗
41. 10.1021/jacs.5b0161310.1021/jacs.5b01613 ↗
42. 10.1021/acsnano.5b0179010.1021/acsnano.5b01790 ↗
43. 10.1016/j.apcatb.2016.12.01610.1016/j.apcatb.2016.12.016 ↗
44. 10.1039/C7TA00299H10.1039/C7TA00299H ↗
45. 10.1039/C9GC03698A10.1039/C9GC03698A ↗
46. 10.1039/D0SC00136H10.1039/D0SC00136H ↗
47. 10.1021/acscatal.9b0379010.1021/acscatal.9b03790 ↗
48. 10.1016/j.electacta.2014.11.15010.1016/j.electacta.2014.11.150 ↗
49. 10.1016/j.chempr.2016.06.00110.1016/j.chempr.2016.06.001 ↗
50. 10.1016/j.pnsc.2017.03.00110.1016/j.pnsc.2017.03.001 ↗
51. 10.1038/s41467-018-03112-310.1038/s41467-018-03112-3 ↗
52. 10.1103/PhysRevB.54.1116910.1103/PhysRevB.54.11169 ↗
53. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
54. 10.1103/PhysRevB.47.55810.1103/PhysRevB.47.558 ↗
55. 10.1103/physrevb.46.667110.1103/physrevb.46.6671 ↗
56. 10.1103/PhysRevB.87.24540210.1103/PhysRevB.87.245402 ↗
57. 10.1002/chem.20170213010.1002/chem.201702130 ↗
58. 10.1039/C2JM31694C10.1039/C2JM31694C ↗
59. 10.1039/D0TA07793C10.1039/D0TA07793C ↗
60. 10.1016/j.jiec.2012.12.00210.1016/j.jiec.2012.12.002 ↗
61. 10.1021/acssuschemeng.8b0163010.1021/acssuschemeng.8b01630 ↗
62. 10.1351/pac19916305071110.1351/pac199163050711 ↗