journal article·2021-08-23

Simple-Synthesized Sulfonated Ferrocene Ammonium for Aqueous Redox Flow Batteries

Yiwen Yao, He Xu, Zhongzhen Tian, Jing Zhang, Fuxu Zhan, Mei Yan, Chuankun Jia

ACS Applied Energy Materials· Volume 4· Issue 8
Publisher page

Abstract

To achieve sustainable development, the development and utilization of redox-active organic species in aqueous redox flow batteries provide broad prospects for large-scale and sustainable energy storage. Herein, we report a sulfonated ferrocene derivative, ferrocene ammonium sulfonate, that is stable and easy to synthesize. We applied it as a catholyte in zinc hybrid flow batteries. Through the adjustment of the electrolyte, the battery showed high capacity retention and efficiency. When the current density was 20 mA/cm2 and 0.5 M NaCl + 0.5 M NH4Cl solution was used as the supporting electrolyte, the capacity retention reached 92.55% after 100 consecutive charge/discharge cycles. In addition, the coulombic efficiency, energy efficiency, and voltage efficiency stayed at 98.33, 83.19, and 84.60%, respectively. This battery design puts forward an idea for developing low-cost materials and improving capacity retention.
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Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Technologies Research · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China

College of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, P. R. China

School of Chemistry and Chemical Engineering, Inner Mongolia University of Science & Technology, Baotou 014010, P. R. China

Funding

Changsha University of Science??and??Technology · Taishan Scholar Project of Shandong Province · University of Jinan · National Natural Science Foundation of China · Natural Science Foundation of Shandong Province · Project of ???20 items of University??? of Jinan · Case-by-Case Project for Top Outstanding Talents of Jinan · Department of Chemistry, Qingdao University of Science and Technology

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