Carboxylation of α,β-Unsaturated Ketones by CO2 Fixation through Photoelectro-chemistry
Source abstract
Abstract
One-step synthesis of β-carboxyl ketones from α,β-unsaturated ketones using CO2 as a feedstock by photoelectro-synergetic catalysis is reported herein. In this ambient system, silica nanowires (SiNWs) electrode not only acts as the working electrode but also harvests extra light energy to promote the reaction. Following a possible two-step single-electron-transfer process, various substrates exhibit good efficiency with up to 98% product yield, and the method shows wide functional group tolerance.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Carbon dioxide utilization in catalysis · CO2 Reduction Techniques and Catalysts · Ionic liquids properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu,People’s Republic of China
Department of Chemistry, Mercket Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States
Funding
National Natural Science Foundation of China · Recruitment Program of Global Experts · National Science Foundation · Jiangsu Provincial Foundation for Specially-Appointed Professor · Start-up Fund from Nanjing Tech University
References (39)
Show source-provided references
1. 10.1126/science.aam628410.1126/science.aam6284 ↗
2. 10.1039/B804323J10.1039/B804323J ↗
3. 10.1039/C8SC05539D10.1039/C8SC05539D ↗
4. 10.1002/asia.20190180210.1002/asia.201901802 ↗
5. 10.1016/j.cclet.2019.10.04110.1016/j.cclet.2019.10.041 ↗
6. 10.1016/j.cclet.2019.11.00110.1016/j.cclet.2019.11.001 ↗
7. 10.1039/C5CC02403J10.1039/C5CC02403J ↗
8. 10.1039/C7TA07290B10.1039/C7TA07290B ↗
9. 10.1039/C8CC04735A10.1039/C8CC04735A ↗
10. 10.1016/j.rser.2013.11.04510.1016/j.rser.2013.11.045 ↗
11. 10.1039/c0cs00129e10.1039/c0cs00129e ↗
12. 10.1039/C7GC00199A10.1039/C7GC00199A ↗
13. 10.1021/jacs.7b0594210.1021/jacs.7b05942 ↗
14. 10.1002/chem.20180052610.1002/chem.201800526 ↗
15. 10.1021/jacs.5b0551310.1021/jacs.5b05513 ↗
16. 10.1021/acs.orglett.7b0187710.1021/acs.orglett.7b01877 ↗
17. 10.1021/jacs.5b1003210.1021/jacs.5b10032 ↗
18. 10.1021/jacs.8b0156110.1021/jacs.8b01561 ↗
19. 10.1002/ejoc.20180136410.1002/ejoc.201801364 ↗
20. 10.1021/ja103429q10.1021/ja103429q ↗
21. 10.1002/anie.20100712810.1002/anie.201007128 ↗
22. 10.1021/ol201193d10.1021/ol201193d ↗
23. 10.1002/anie.20130452910.1002/anie.201304529 ↗
24. 10.1002/ange.20080185710.1002/ange.200801857 ↗
25. 10.1016/j.cogsc.2016.10.00310.1016/j.cogsc.2016.10.003 ↗
26. 10.1039/c3cc47221c10.1039/c3cc47221c ↗
27. 10.1021/acs.orglett.7b0105510.1021/acs.orglett.7b01055 ↗
28. 10.1021/acs.orglett.5b0261910.1021/acs.orglett.5b02619 ↗
29. 10.1002/anie.20120256910.1002/anie.201202569 ↗
30. 10.1002/anie.20121022810.1002/anie.201210228 ↗
31. 10.1021/nl071018b10.1021/nl071018b ↗
32. 10.1021/nl100161z10.1021/nl100161z ↗
33. 10.1063/1.327579810.1063/1.3275798 ↗
34. 10.1117/1.276899910.1117/1.2768999 ↗
35. 10.3109/14756366.2012.73338410.3109/14756366.2012.733384 ↗
36. 10.1016/j.bioorg.2017.02.00610.1016/j.bioorg.2017.02.006 ↗
37. 10.1021/jo101388x10.1021/jo101388x ↗
38. 10.1002/jccs.20080018510.1002/jccs.200800185 ↗
39. 10.1021/ja00044a01810.1021/ja00044a018 ↗