journal article·2020-03-23

N-Doping Holey Graphene TiO2–Pt Composite as Efficient Electrocatalyst for Methanol Oxidation

Rongli Cui, Shuaichao Liu, Xihong Guo, Huan Huang, Jiahao Wang, Bing Liu, Ying Li, Dangui Zhao, Jinquan Dong, Baoyun Sun

ACS Applied Energy Materials· Volume 3· Issue 3
Publisher page

Abstract

The nitrogen-doped holey graphene oxide/TiO2 (TiO2–NHGO) composite is synthesized as catalyst support for the Pt catalyst. The resulting catalyst, Pt–TiO2–rNHGO, shows higher activity and stability for methanol electrooxidation than the Pt–rGO, Pt–rHGO, and Pt–rNHGO catalysts. The enhancement is because of the combinatory effect of nanoholes in the graphene plane which provide more active sites and efficient mass transport, well-distributed N-doping, and the uniform distribution of TiO2 NPs on NHGO nanosheets which facilitate to form more uniformly dispersed Pt NPs. In addition, the strong interactions among Pt, TiO2, and NHGO also contribute to enhance the performance of catalyst for methanol oxidation.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory for Biomedical Effects of Nanomaterial & Nanosafety, Institute of High Energy Physics, Chinese Academy of Science (CAS), Beijing 100049, China

College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Institute of High Energy Physics, Chinese Academy of Sciences

References (64)

Show source-provided references
1. 10.1038/nature1147510.1038/nature11475 ↗
2. 10.1002/aenm.20160121610.1002/aenm.201601216 ↗
3. 10.1038/ncomms1003510.1038/ncomms10035 ↗
4. 10.1016/j.nanoen.2013.06.00910.1016/j.nanoen.2013.06.009 ↗
5. 10.1021/acscatal.8b0036610.1021/acscatal.8b00366 ↗
6. 10.3390/catal702004710.3390/catal7020047 ↗
7. 10.1038/ncomms322110.1038/ncomms3221 ↗
8. 10.1021/cr900390210.1021/cr9003902 ↗
9. 10.1021/cr400389f10.1021/cr400389f ↗
10. 10.1039/C8TA06071A10.1039/C8TA06071A ↗
11. 10.1039/c1ee01307f10.1039/c1ee01307f ↗
12. 10.1038/3510462010.1038/35104620 ↗
13. 10.1039/C9CC06004A10.1039/C9CC06004A ↗
14. 10.1002/smll.20060063610.1002/smll.200600636 ↗
15. 10.1021/acs.jpcc.6b1088210.1021/acs.jpcc.6b10882 ↗
16. 10.1016/j.carbon.2015.06.02210.1016/j.carbon.2015.06.022 ↗
17. 10.1016/j.carbon.2014.08.01310.1016/j.carbon.2014.08.013 ↗
18. 10.1021/cm901542w10.1021/cm901542w ↗
19. 10.1002/anie.20060130110.1002/anie.200601301 ↗
20. 10.1002/anie.20090089910.1002/anie.200900899 ↗
21. 10.1039/C7TA05102F10.1039/C7TA05102F ↗
22. 10.1021/acsami.7b0786610.1021/acsami.7b07866 ↗
23. 10.1002/adma.20140187710.1002/adma.201401877 ↗
24. 10.1016/j.carbon.2012.09.01910.1016/j.carbon.2012.09.019 ↗
25. 10.1002/adfm.20100160210.1002/adfm.201001602 ↗
26. 10.1039/c0cc00394h10.1039/c0cc00394h ↗
27. 10.1016/j.carbon.2009.11.03410.1016/j.carbon.2009.11.034 ↗
28. 10.1021/nn901448310.1021/nn9014483 ↗
29. 10.1016/j.elecom.2009.04.00110.1016/j.elecom.2009.04.001 ↗
30. 10.1016/j.jpowsour.2007.06.08410.1016/j.jpowsour.2007.06.084 ↗
31. 10.1149/1.316057210.1149/1.3160572 ↗
32. 10.1039/C3EE43886D10.1039/C3EE43886D ↗
33. 10.1002/adma.20080130610.1002/adma.200801306 ↗
34. 10.1039/C3TA14754A10.1039/C3TA14754A ↗
35. 10.1039/C5CC07482G10.1039/C5CC07482G ↗
36. 10.1002/celc.20180139510.1002/celc.201801395 ↗
37. 10.1016/j.jpowsour.2014.12.09610.1016/j.jpowsour.2014.12.096 ↗
38. 10.1016/j.carbon.2014.01.06210.1016/j.carbon.2014.01.062 ↗
39. 10.1016/j.carbon.2010.03.00410.1016/j.carbon.2010.03.004 ↗
40. 10.1039/C5TA08585C10.1039/C5TA08585C ↗
41. 10.1016/j.elecom.2007.06.03210.1016/j.elecom.2007.06.032 ↗
42. 10.1039/c2jm00144f10.1039/c2jm00144f ↗
43. 10.1016/j.jpowsour.2010.08.11810.1016/j.jpowsour.2010.08.118 ↗
44. 10.1039/c3ta14418f10.1039/c3ta14418f ↗
45. 10.1002/anie.20160064710.1002/anie.201600647 ↗
46. 10.1002/cctc.20130064710.1002/cctc.201300647 ↗
47. 10.1021/cr500008u10.1021/cr500008u ↗
48. 10.1039/C1CP23367J10.1039/C1CP23367J ↗
49. 10.1021/acs.nanolett.5b0121210.1021/acs.nanolett.5b01212 ↗
50. 10.1038/srep2985410.1038/srep29854 ↗
51. 10.1002/smll.20140340210.1002/smll.201403402 ↗
52. 10.1126/science.aam585210.1126/science.aam5852 ↗
53. 10.1007/s12274-014-0613-x10.1007/s12274-014-0613-x ↗
54. 10.1016/j.jpowsour.2014.01.00110.1016/j.jpowsour.2014.01.001 ↗
55. 10.1149/1.273207410.1149/1.2732074 ↗
56. 10.1126/science.117033510.1126/science.1170335 ↗
57. 10.1039/c2jm32816j10.1039/c2jm32816j ↗
58. 10.1021/acsomega.8b0261010.1021/acsomega.8b02610 ↗
59. 10.1021/nn200766e10.1021/nn200766e ↗
60. 10.1016/j.jechem.2017.12.00610.1016/j.jechem.2017.12.006 ↗
61. 10.1039/C6NR08139H10.1039/C6NR08139H ↗
62. 10.1039/C9NR01732A10.1039/C9NR01732A ↗
63. 10.1002/aenm.20160120810.1002/aenm.201601208 ↗
64. 10.1021/acsami.7b1900910.1021/acsami.7b19009 ↗