journal article·2018-11-26

Biogenic Reduction of Graphene Oxide: An Efficient Superparamagnetic Material for Photocatalytic Hydrogen Production

Neeta Gurbani, Chih-Pin Han, Kazuhiro Marumoto, Ru-Shi Liu, Ram Janay Choudhary, Neelu Chouhan

ACS Applied Energy Materials· Volume 1· Issue 11
Publisher page

Abstract

Here, we present the reduction of the graphene oxide (GO) sheets by means of the two reducing agents, i.e., ascorbic acid and lemon juice. As-prepared carbonaceous substances (rGO-AA and rGO-Lemon) exhibits good room temperature (RT) ferromagnetism even in absence of d- and f-electrons as well as they show good hydrogen generation capacity via photocatalytic water splitting. The amount of H2 evolved for Pt/GO, Pt/rGO-AA, and Pt/rGO-Lemon systems was 32.0790, 23.1649, and 38.0790 mmol h–1 g–1, respectively. The results go hand in hand and are supported by the reasonably good spin concentration due to the presence of a large amount of the free-radical-like carbon, long-range direct/indirect exchange or interaction between graphene matrix, fragmented graphitic zones, C-defect nonbonding localized electronic states, and flat-band quasi-localized (QL) states induced by the point defects.
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Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Pure and Applied Chemistry, University of Kota, MBS Road, Viviekanand Nagar, Kota 324005, India

Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

Department of Mechanical Engineering and Graduate Institute of Manufacturing Technology, National Taipei University of Technology, Taipei 106, Taiwan

UGC, DAE-CSR, Devi Ahiliya University Campus, Khandwa Road, Indore 452017, India

Funding

University Grants Commission · Department of Atomic Energy, Government of India · Science and Engineering Research Board · Ministry of Science and Technology, Taiwan

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