journal article·2020-02-24

Cadmium Hydroxide: A Missing Non-Noble Metal Hydroxide Electrocatalyst for the Oxygen Evolution Reaction

Xiang Chen, Haonan Wang, Ruru Meng, Bin Xia, Zuju Ma

ACS Applied Energy Materials· Volume 3· Issue 2
Publisher page

Abstract

An emerging non-noble-metal-based oxygen evolution reaction (OER) electrocatalyst, cadmium hydroxide (Cd(OH)2), has been developed in this work; this was prepared via a facile chemical precipitation method by using cadmium salt as the precursor. Without using a noble or first-row transition metal element, the as-obtained Cd(OH)2 nanoplate electrocatalyst exhibits an impressive electrocatalytic OER performance with a low overpotential of 266 mV at the current density of 10 mA/cm2, a low Tafel slope of 47 mV/dec, and considerable stability, results which are superior to those of noble-metal-based commercial RuO2, and comparable to those of a commonly used first-row transition-metal-based catalyst Co(OH)2.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Metallurgical Emission Reduction & Resources Recycling, Anhui University of Technology, Ministry of Education, Maanshan 243002, P. R. China

School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, P. R. China

Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Anhui University of Technology, Ministry of Education, Maanshan 243002, P. R. China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Anhui Province · Anhui University of Technology

References (22)

Show source-provided references
1. 10.1039/C4CS00470A10.1039/C4CS00470A ↗
2. 10.1038/s41560-018-0132-110.1038/s41560-018-0132-1 ↗
3. 10.1002/adma.20180668210.1002/adma.201806682 ↗
4. 10.1039/C9EE01202H10.1039/C9EE01202H ↗
5. 10.1039/C6CS00328A10.1039/C6CS00328A ↗
6. 10.1021/jacs.9b0121410.1021/jacs.9b01214 ↗
7. 10.1002/adma.20160227010.1002/adma.201602270 ↗
8. 10.1038/s41929-017-0004-210.1038/s41929-017-0004-2 ↗
9. 10.1002/adma.20150269610.1002/adma.201502696 ↗
10. 10.1002/smll.20180420110.1002/smll.201804201 ↗
11. 10.1016/j.jechem.2018.09.01310.1016/j.jechem.2018.09.013 ↗
12. 10.1039/c2nj41054k10.1039/c2nj41054k ↗
13. 10.1039/C6TA09959A10.1039/C6TA09959A ↗
14. 10.1039/C9CC06863E10.1039/C9CC06863E ↗
15. 10.1038/s41560-019-0355-910.1038/s41560-019-0355-9 ↗
16. 10.1002/aenm.20180335810.1002/aenm.201803358 ↗
17. 10.1021/acsami.9b1031510.1021/acsami.9b10315 ↗
18. 10.1016/j.apcatb.2018.01.07810.1016/j.apcatb.2018.01.078 ↗
19. 10.1016/j.jlumin.2009.09.02210.1016/j.jlumin.2009.09.022 ↗
20. 10.1039/C4TA06634K10.1039/C4TA06634K ↗
21. 10.1038/s41467-019-09191-010.1038/s41467-019-09191-0 ↗
22. 10.1021/ja407115p10.1021/ja407115p ↗