journal article·2018-02-26

Photon Up-Conversion via Epitaxial Surface-Supported Metal–Organic Framework Thin Films with Enhanced Photocurrent

Shargeel Ahmad, Jinxuan Liu, Chenghuan Gong, Jianzhang Zhao, Licheng Sun

ACS Applied Energy Materials· Volume 1· Issue 2
Publisher page

Abstract

We report a new triplet–triplet annihilation photon up-conversion (TTA-UC) system using an epitaxial Zn-perylene surface-supported metal–organic framework (SURMOF) grown on metal oxide surface as “emitter”, and a platinum octaethylporphyrin (PtOEP) as “sensitizer” in [Co(bpy) 3 ] 2+/3+ acetonitrile solution. It has been demonstrated that the photocurrent can be significantly enhanced relative to epitaxial Zn-perylene SURMOF due to the TTA-UC mechanism. This initial result holds promising applications toward SURMOF-based solar energy conversion devices.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials · Nanoplatforms for cancer theranostics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, Dalian University of Technology, 116024 Dalian, China

Department of Chemistry, School of Chemical Science and Engineering, KTH Royal Institute of Technology, 10044 Stockholm, Sweden

Funding

Ministry of Science and Technology of the People's Republic of China · Ministry of Education of the People's Republic of China · National Natural Science Foundation of China · State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University

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