journal article·2019-08-26

Pt/Co3O4 Surpasses Benchmark Pt/C: An Approach Toward Next Generation Hydrogen Evolution Electrocatalyst

Rajkumar Jana, Chandra Chowdhury, Sudip Malik, Ayan Datta

ACS Applied Energy Materials· Volume 2· Issue 8
Publisher page

Abstract

Rational design of composite hybrid structures tuned in atomic level interaction can circumvent the instability of the water splitting catalysts. Here, low-temperature aqueous phase synthesis of a hybrid hydrogen evolution electrocatalyst made of a few nanometer Pt clusters anchored on Co3O4 nanosheets with remarkable stability and superiority over the state-of-the-art Pt/C is achieved. Manipulation of cluster binding energy to support material gives rise to superior activity (3.8 times) and extraordinarily enhanced durability. Pt/Co3O4 composite achieved current densities of 10 and 50 mA/cm2 at overpotentials as low as of 70 and 170 mV, respectively. A combinatorial approach of theory and experiment opens an avenue to design HER catalyst beyond Pt/C.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced Photocatalysis Techniques · Advanced battery technologies research

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