DataVXACS Applied Energy MaterialsPaper
journal article·2019-06-24Open access

Dual-Ligand Fe-Metal Organic Framework Based Robust High Capacity Li Ion Battery Anode and Its Use in a Flexible Battery Format for Electro-Thermal Heating

Neha Sharma, Sabine Szunerits, Rabah Boukherroub, Ran Ye, Sorin Melinte, Musthafa Ottakam Thotiyl, Satishchandra Ogale

ACS Applied Energy Materials· Volume 2· Issue 6
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Source abstract

Abstract

Metal organic frameworks (MOFs) have been attracting recent scientific attention as battery electrode materials due to the ease of tailoring their structure, porosity, and properties by varying the organic linkers. In this work, we demonstrate that the use of a Fe-MOF, specifically configured with two ligands, exhibits an impressively high capacity and stability as Li ion battery anode, with the use of earth abundant Fe being an added advantage. Thus, a specific capacity of 825 mAh g–1 is realized at 250 mA g–1 at the end of 100 cycles with an excellent stability of 1000 cycles at 2 A g–1. The full (coin) cell device delivered 360 Wh/kg at 500 mA g–1 with a long-term stability of 1000 cycles and charging capability in just 2 min. A flexible Li ion battery with this Fe-MOF and LiCoO2 cathode could quickly heat a flexible electro-thermal heater for drug delivery.
Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics and Centre for Energy Science, Indian Institute of Science Education and Research (IISER), Dr. Homi Bhabha Road, Pashan, Pune, Maharashtra 411008, India

CNRS, Centrale Lille, ISEN, Univ. Valenciennes, UMR 8520-IEMN, Univ. Lille, Lille 59000, France

Institute of Information and Communication Technologies, Electronics and Applied Mathematics, Université Catholique de Louvain, Louvain-la-Neuve 1348, Belgium

Department of Chemistry and Centre for Energy Science, Indian Institute of Science Education and Research (IISER), Dr. Homi Bhabha Road, Pashan, Pune, Maharashtra 411008, India

Funding

Department of Atomic Energy, Government of India · Department of Science and Technology, Ministry of Science and Technology

References (43)

Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. 10.1038/nenergy.2016.7410.1038/nenergy.2016.74 ↗
3. 10.1039/C6TA03166H10.1039/C6TA03166H ↗
4. 10.1038/3510464410.1038/35104644 ↗
5. 10.1149/2.0251701jes10.1149/2.0251701jes ↗
6. 10.1002/adma.20150108810.1002/adma.201501088 ↗
7. 10.1002/adma.20120192010.1002/adma.201201920 ↗
8. 10.1038/nmat480810.1038/nmat4808 ↗
9. 10.1016/j.jpowsour.2017.06.07410.1016/j.jpowsour.2017.06.074 ↗
10. 10.1007/978-3-319-17031-2_210.1007/978-3-319-17031-2_2 ↗
11. 10.1039/c0jm04225k10.1039/c0jm04225k ↗
12. 10.1016/j.jpowsour.2006.01.01510.1016/j.jpowsour.2006.01.015 ↗
13. 10.1021/acsami.7b0588910.1021/acsami.7b05889 ↗
14. 10.1002/anie.20060516310.1002/anie.200605163 ↗
15. 10.1149/2.0681903jes10.1149/2.0681903jes ↗
16. 10.1016/j.mattod.2016.10.00310.1016/j.mattod.2016.10.003 ↗
17. 10.1016/j.chempr.2016.12.00210.1016/j.chempr.2016.12.002 ↗
18. 10.1021/nn501783n10.1021/nn501783n ↗
19. 10.1039/c3ta12621h10.1039/c3ta12621h ↗
20. 10.1021/nl302618s10.1021/nl302618s ↗
21. 10.1039/C6RA01645F10.1039/C6RA01645F ↗
22. 10.1016/j.electacta.2017.03.10510.1016/j.electacta.2017.03.105 ↗
23. 10.1039/C4TA06694D10.1039/C4TA06694D ↗
24. 10.1039/C5TA10467J10.1039/C5TA10467J ↗
25. 10.1007/978-1-4614-9434-810.1007/978-1-4614-9434-8 ↗
26. 10.3390/s15112888910.3390/s151128889 ↗
27. 10.1561/100000002910.1561/1000000029 ↗
28. 10.1002/9780471740360.ebs136910.1002/9780471740360.ebs1369 ↗
29. 10.1016/j.electacta.2012.03.05710.1016/j.electacta.2012.03.057 ↗
30. 10.1039/c0ee00640h10.1039/c0ee00640h ↗
31. 10.1038/srep0162210.1038/srep01622 ↗
32. 10.1021/nl300794f10.1021/nl300794f ↗
33. 10.1021/nn101815810.1021/nn1018158 ↗
34. 10.1021/nl302254v10.1021/nl302254v ↗
35. 10.1016/j.jpowsour.2014.10.18310.1016/j.jpowsour.2014.10.183 ↗
36. 10.1039/c3ee44164d10.1039/c3ee44164d ↗
37. 10.1039/C5DT00021A10.1039/C5DT00021A ↗
38. 10.1016/j.jallcom.2018.05.31510.1016/j.jallcom.2018.05.315 ↗
39. 10.1557/jmr.2017.32910.1557/jmr.2017.329 ↗
40. 10.1021/jacs.8b1138910.1021/jacs.8b11389 ↗
41. 10.1021/nl501154210.1021/nl5011542 ↗
42. 10.1038/s41377-018-0038-510.1038/s41377-018-0038-5 ↗
43. 10.1021/acsami.7b1294910.1021/acsami.7b12949 ↗