journal article·2018-11-26

Facile Synthesis of Nitrogen-Rich Porous Organic Polymers for Latent Heat Energy Storage

Jiahuan Li, Zhonghua Cheng, Meifang Zhu, Arne Thomas, Yaozu Liao

ACS Applied Energy Materials· Volume 1· Issue 11
Publisher page

Abstract

The development of phase change material (PCM) composites with high latent heat of fusion and good shape-stability have received considerable attention for thermal energy engineering and management. In this work nitrogen-rich porous organic polymers (N-POPs) with high surface areas synthesized via Schiff-base coupling between 1,3,5-triformylbenzene and pararosaniline base are presented, which can take up 85 wt % of 1-octadecanol (ODA) as a PCM. The resulting ODA@N-POPs exhibit a high latent heat of fusion up to 182.7 J/g, satisfying shape-stability, and good reversibility upon 100 heating cycles, which are promising for solar thermal energy engineering and management.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Phase Change Materials Research · Solar-Powered Water Purification Methods

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Affiliations

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Department of Chemistry, Functional Materials, Technische Universität Berlin, Berlin 10623, Germany

Funding

Deutsche Forschungsgemeinschaft · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · Shanghai Municipality

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