journal article·2020-09-28

An Implantable Artificial Protective Layer Enables Stable Sodium Metal Anodes

Shiyang Wang, Yulin Jie, Zhihao Sun, Wenbin Cai, Yawei Chen, Fanyang Huang, Yang Liu, Xinpeng Li, Ruiqi Du, Ruiguo Cao, Genqiang Zhang, Shuhong Jiao

ACS Applied Energy Materials· Volume 3· Issue 9
Publisher page

Abstract

Sodium metal anodes are commonly limited by low Coulombic efficiency and an unstable interface between Na metal and carbonate ester electrolytes. Herein, a freestanding and implantable artificial protective layer with strong mechanical rigidity is reported as a feasible strategy to suppress the dendrite and stabilize the interface, which realizes a high Coulombic efficiency of ∼96% in a carbonate-based electrolyte. Furthermore, the freestanding implantable protective layer enables good cycling performance for the sodium metal battery with only 300% Na metal anode excess under high voltage. This work highlights the importance of the rational design of the interface for high-voltage sodium metal batteries.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Inorganic Chemistry and Materials

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Affiliations

Hefei National Laboratory for Physical Science at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China

Funding

Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Natural Science Foundation of Anhui Province

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