journal article·2020-04-27

Phenothiazine–MXene Aqueous Asymmetric Pseudocapacitors

Muhammad Boota, Matthieu Bécuwe, Yury Gogotsi

ACS Applied Energy Materials· Volume 3· Issue 4
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Abstract

We report here a molecular phenothiazine-based electrode as a high capacitance and long cycle life (77% retention after 80 000 cycles) pseudocapacitive organic material after hydrothermal deposition on reduced graphene oxide (rGO). Given the high stability of phenothiazine coated rGO hybrid electrodes under positive potentials, pseudocapacitive asymmetric supercapacitors were manufactured using two-dimensional titanium carbide (Ti3C2Tx) MXene as the negative electrode, which allowed expansion of the voltage window up to 1.4 V in 3 M H2SO4. The optimized asymmetric pseudocapacitors showed capacitance retention of over 80% after 30 000 cycles at 100 mV/s, which is one of the highest for aqueous asymmetric supercapacitors.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · MXene and MAX Phase Materials · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

A. J. Drexel Nanomaterials Institute and Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19104, United States

Laboratoire de Réactivité et Chimie des Solides (LRCS), UMR CNRS 7314, Université de Picardie Jules Verne (UPJV), 33 rue Saint Leu, 80039 Amiens, France

Institut de Chimie de Picardie (ICP), CNRS FR3085, Université de Picardie Jules Verne, 80039 Amiens Cedex, France

Réseau sur le Stockage Electrochimique de l’Energie (RS2E), FR CNRS 3459, 80039 Amiens, France

Funding

European Commission · Basic Energy Sciences

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