journal article·2018-12-24

Visible-Light Overall Water Splitting by CdS/WO3/CdWO4 Tricomposite Photocatalyst Suppressing Photocorrosion

Haruki Nagakawa, Tsuyoshi Ochiai, Seiji Konuma, Morio Nagata

ACS Applied Energy Materials· Volume 1· Issue 12
Publisher page

Abstract

Photocatalytic water splitting under visible light has attracted attention as a possible solution to the energy exhaustion problem. Hitherto, water splitting has been generally achieved using several oxynitrides, oxysulfides, and nitrides, and only a few studies report water splitting using cadmium sulfide (CdS) as a photocatalyst. A major reason for this is that CdS undergoes photocorrosion. In this study, we achieved an overall water splitting under visible light using a CdS/WO3/CdWO4 tricomposite photocatalyst. In the process, photocorrosion of CdS was suppressed by covering it with WO3 and CdWO4, and the oxidation reaction progressed in WO3 by the Z-scheme type photocatalytic reaction.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Advanced biosensing and bioanalysis techniques · Advanced Nanomaterials in Catalysis

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Affiliations

Department of Industrial Chemistry, Graduate School of Engineering, Tokyo University of Science, 12-1 Ichigayafunagawara-cho, Shinjuku-ku, Tokyo 162-0826, Japan

Photocatalyst Group, Research and Development Department, Local Independent Administrative Agency Kanagawa Institute of industrial Science and TEChnology (KISTEC), Kanagawa 213-0012, Japan

Materials Analysis Group, Kawasaki Technical Support Department, KISTEC, Kanagawa 213-0012, Japan

Photocatalysis International Research Center, Tokyo University of Science, Chiba 278-8510, Japan

Nanostructure Analysis Group, Kawasaki Technical Support Department, KISTEC, Kanagawa 213-0012, Japan

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