journal article·2024-08-26Open access

All Platinum-Group-Metal-Free Alkaline Exchange Membrane Water Electrolyzers Using Direct Hydrothermal Catalyst Deposition on Raney Ni Substrate

Malte Klingenhof, Sören Selve, Christian M. Günther, Johannes Schmidt, Fatemeh Razmjooei, Peter Strasser, Syed-Asif Ansar

ACS Applied Energy Materials· Volume 7· Issue 16

Abstract

High Resolution Image Download MS PowerPoint Slide Green hydrogen produced via water electrolysis powered by renewable energy sources promises the decarbonization of large sectors of the economy. Despite alkaline environments that enable use of non-noble, abundant materials, state-of-the-art anion exchange membrane water electrolyzers (AEMWEs) uses noble-metal-based catalysts. Developing non-noble-metal-based anodes would enhance the competitiveness of AEMWEs. Herein, an anode fabricated by hydrothermal deposition of binder-free NiFe-LDH onto Raney Ni (RNi) substrates is described. The introduced platinum-group-metal-free AEMWEs display high performance of 1 A cm –2 at 1.9 V cell voltage. Physicochemical characterization highlights the successful combination of NiFe-LDH with RNi applying a scalable synthesis offering feasibility to fabricate active and durable electrodes for AEMWEs.
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Research context

OpenAlex topics: Fuel Cells and Related Materials · Hybrid Renewable Energy Systems · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The Electrochemical Energy, Catalysis, and Materials Science Laboratory, Department of Chemistry, Chemical Engineering Division, Technical University Berlin, Straße des 17 Juni 124, 10623 Berlin, Germany

Center for Electron Microscopy (ZELMI), Technical University Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany

Department of Chemistry/Functional Materials, Technical University Berlin, Hardenbergstraße 40, 10623 Berlin, Germany

Institute of Engineering Thermodynamics, German Aerospace Center, Pfaffenwaldring 38-40, 70569 Stuttgart, Germany

Funding

Bundesministerium f?r Bildung und Forschung

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