Ultralong-Life Quinone-Based Porous Organic Polymer Cathode for High-Performance Aqueous Zinc-Ion Batteries
Source abstract
Abstract
High Resolution Image Download MS PowerPoint Slide We synthesized and studied a redox-active quinone-based porous organic polymer (rPOP) and found ultralong cycle life: it is a promising organic cathode for aqueous zinc-ion batteries (ZIBs). It has high physicochemical stability and enhanced intrinsic conductivity from its fused-aromatic conjugated skeleton. rPOP’s high porosity allows for efficient Zn 2+ infiltration through the pores during charging–discharging cycles and contributes to the efficient utilization of redox-active quinone units. It delivers a specific capacity of 120 mAh g –1 at a current density of 0.1 A g –1 with a flat and long discharge plateau, which is critically important to provide a stable voltage output. It provides ultralong cycle life at a current density of 1.0 A g –1 for 1000 and at 2.0 A g –1 for 30 000 cycles, with initial capacity retention of 95 and 66%, respectively. The co-insertion (Zn 2+ and H + ) charge storage mechanism was investigated using various electrochemical measurements and ex/in situ structural characterization techniques, and is explained herein. These findings contribute to a better understanding of the structure–property relationship for rPOP and open a new avenue for new organic cathode materials for high-performance next-generation aqueous batteries.
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Research context
OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Advancements in Battery Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Izmir Institute of Technology, Izmir 35430, Turkey
Department of Chemistry, Eskisehir Osmangazi University, Eskisehir 26040, Turkey
Center for Multidimensional Carbon Materials, Institute for Basic Science (IBS), Ulsan 44919, Republic of Korea
Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
National Creative Research Initiative Center for Multi-Dimensional Directed Nanoscale Assembly, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea
Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea
Funding
Institute for Basic Science · T?rkiye Bilimsel ve Teknolojik Arastirma Kurumu
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