journal article·2022-01-24

Comparative Study of the Thermal Stability of Electrode Materials for Li-Ion and Na-Ion Batteries

Ruslan R. Samigullin, Oleg A. Drozhzhin, Evgeny V. Antipov

ACS Applied Energy Materials· Volume 5· Issue 1
Publisher page

Abstract

The thermal stability of the cathode and anode materials for Li-ion and Na-ion batteries─LiNi1/3Mn1/3Co1/3O2, LiFePO4, Li4Ti5O12, graphite, O3-NaNi1/3Fe1/3Mn1/3O2 (NFM), Na3V2(PO4)3 (NVP), β-NaVP2O7 (NVPO), Na3V2(PO4)2F3 (NVPF), and hard carbon─was studied by means of differential scanning calorimetry of the electrodes in the charged state and ex situ powder X-ray diffraction. The obtained results indicate that the thermal stability of the Na-ion cathode materials increases in the order NFM < NVPF < NVP < NVPO. The “heat on energy” term has been proposed and analyzed for all of the studied materials.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Extraction and Separation Processes

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Affiliations

Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russian Federation

Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Moscow 143026, Russian Federation

Funding

Russian Science Foundation · Russian Foundation for Basic Research

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